13537-92-3

Basic information

• Product Name: ethyl 1,4-dimethyl-2-oxocyclohexane-1-carboxylate
• Synonyms: ethyl 1,4-dimethyl-2-oxocyclohexane-1-carboxylate
• CAS NO: 13537-92-3
• Molecular Weight: 198.262
• Mol File: 13537-92-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 1,4-dimethyl-2-oxocyclohexane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 1,4-dimethyl-2-oxocyclohexane-1-carboxylate(13537-92-3)
• EPA Substance Registry System: ethyl 1,4-dimethyl-2-oxocyclohexane-1-carboxylate(13537-92-3)

Safety Data

• Hazardous Substances Data: 13537-92-3(Hazardous Substances Data)

Upstream product

• 54044-86-9 2-acetyl-2-methyl-hex-5-enoic acid ethyl ester 
• 14619-42-2 ethyl 4-methyl-2-oxocyclohex-3-ene-1-carboxylate 
• 75-03-6 ethyl iodide 
• 74-88-4 methyl iodide 
• 13537-82-1 ethyl 4-methyl-2-cyclohexanone-1-carboxylate 
• 74-83-9 methyl bromide 

Relevant articles and documents

Zinc-mediated anionic cyclization of unstabilized ketone enolates with unactivated alkenes

We report herein general conditions for a zinc-mediated anionic cyclization of unstabilized ketone enolates. This anionic cyclization allows access to various carbocyclic architectures by utilizing abundant ketones and unactivated alkenes as precursors. The transformation is enabled by the use of Zn(TMP)2 as base and Zn(OTf)2 as an additive. The resulting alkylzinc species can be intercepted by electrophiles for tandem C–X and C–O bond formation.

The cyclization of 2-p-tosyloxymethylene-2-benzyloxymethylene-5-methyl-1-cyclohexanone

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