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ethyl 1,4-dimethyl-2-oxocyclohexane-1-carboxylate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

13537-92-3

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13537-92-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 13537-92-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,5,3 and 7 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 13537-92:
(7*1)+(6*3)+(5*5)+(4*3)+(3*7)+(2*9)+(1*2)=103
103 % 10 = 3
So 13537-92-3 is a valid CAS Registry Number.

13537-92-3Downstream Products

13537-92-3Relevant academic research and scientific papers

Zinc-mediated anionic cyclization of unstabilized ketone enolates with unactivated alkenes

Olivieri, Diego,Huang, David,Bodnar, Alexandra K.,Yu, Shijin,Newhouse, Timothy R.

, (2020)

We report herein general conditions for a zinc-mediated anionic cyclization of unstabilized ketone enolates. This anionic cyclization allows access to various carbocyclic architectures by utilizing abundant ketones and unactivated alkenes as precursors. The transformation is enabled by the use of Zn(TMP)2 as base and Zn(OTf)2 as an additive. The resulting alkylzinc species can be intercepted by electrophiles for tandem C–X and C–O bond formation.

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