135384-04-2Relevant academic research and scientific papers
STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-TETRAPONERINE-8
Merlin, P.,Braekman, J. C.,Daloze, D.
, p. 3805 - 3816 (1991)
A stereocontrolled total synthesis of the ant alkaloid (+/-)-tetraponerine-8 (1) has been achieved in 7 steps and 28 percent overall yield, starting from 1-hydroxypiperidine.Key steps are a 1,3-dipolar cycloaddition (3 + 4 -> 5), a nucleophilic substituti
