Tetrahedron p. 3805 - 3816 (1991)
Update date:2022-08-04
Topics:
Merlin, P.
Braekman, J. C.
Daloze, D.
A stereocontrolled total synthesis of the ant alkaloid (+/-)-tetraponerine-8 (1) has been achieved in 7 steps and 28 percent overall yield, starting from 1-hydroxypiperidine.Key steps are a 1,3-dipolar cycloaddition (3 + 4 -> 5), a nucleophilic substituti
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