STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-TETRAPONERINE-8

DOI: 10.1016/S0040-4020(01)80905-4

Source and publish data:

Tetrahedron p. 3805 - 3816 (1991)

Update date:2022-08-04

Topics:

Authors:

Merlin, P.

Braekman, J. C.

Daloze, D.

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Article abstract of DOI:10.1016/S0040-4020(01)80905-4

A stereocontrolled total synthesis of the ant alkaloid (+/-)-tetraponerine-8 (1) has been achieved in 7 steps and 28 percent overall yield, starting from 1-hydroxypiperidine.Key steps are a 1,3-dipolar cycloaddition (3 + 4 -> 5), a nucleophilic substituti

Full text of DOI:10.1016/S0040-4020(01)80905-4

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