1354826-63-3

Basic information

• Product Name: (3R,4R,5R,6S,7S) 7-allyl-1-benzyl-4,5,6-tris(benzyloxy)azepan-3-ol
• Synonyms: (3R,4R,5R,6S,7S) 7-allyl-1-benzyl-4,5,6-tris(benzyloxy)azepan-3-ol
• CAS NO: 1354826-63-3
• Molecular Weight: 563.737
• Mol File: 1354826-63-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3R,4R,5R,6S,7S) 7-allyl-1-benzyl-4,5,6-tris(benzyloxy)azepan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R,5R,6S,7S) 7-allyl-1-benzyl-4,5,6-tris(benzyloxy)azepan-3-ol(1354826-63-3)
• EPA Substance Registry System: (3R,4R,5R,6S,7S) 7-allyl-1-benzyl-4,5,6-tris(benzyloxy)azepan-3-ol(1354826-63-3)

Safety Data

• Hazardous Substances Data: 1354826-63-3(Hazardous Substances Data)

Upstream product

• 223912-28-5 allyl 6-azido-2,3,4-tri-O-benzyl-6-deoxy-β-D-glucopyranoside 
• 1357297-00-7 allyl 6-azido-6-deoxy-β-D-glucopyranoside 
• 223912-26-3 allyl 6-(4-methylbenzenesulfonate)-β-D-glucopyranoside 
• 10343-15-4 Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-allyloxy-tetrahydro-pyran-4-yl ester 
• 604-69-3 β-D-glucose pentaacetate 
• 7177-79-9 methyl 2,3-O-dibenzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 100-39-0 benzyl bromide 
• 1354826-55-3 (1R,2R,3S,4R,5R)-2,3,4-tris(benzyloxy)-8-oxa-6-azabicyclo[3.2.1]octane 
• 19139-89-0 (2R,3R,4S,5R,6S)-2-Azidomethyl-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran 
• 114219-26-0 methyl 2,3,4-tri-O-benzyl-6-O-(4-methylbenzenesulfonyl)-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 

Downstream Products

• 1354826-73-5 (2S,3S,4R,5S,6R)-2-allyl-1-benzyl-3,4,5-tris(benzyloxy)-6-fluoroazepane 
• 1354826-71-3 (2S,3S,4R,5R,6R)-2-allyl-1-benzyl-3,4,5-tris(benzyloxy)-6-(fluoromethyl)piperidine 
• 1354826-75-7 (2S,3S,4R,5R,6R)-2-allyl-6-azido-1-benzyl-3,4,5-tris(benzyloxy)azepane 
• 1354826-74-6 (2S,3S,4R,5R,6S)-2-allyl-6-(azidomethyl)-1-benzyl-3,4,5-tris(benzyloxy)piperidine 
• 1354826-65-5 (2S,3S,4R,5R,6R)-2-allyl-1-benzyl-3,4,5-tris(benzyloxy)-6-(chloromethyl)piperidine 
• 1449009-42-0 ((2S,3R,4R,5S,6S)-6-allyl-1-benzyl-3,4,5-tris(benzyloxy)piperidin-2-yl)methanol 
• 860264-32-0 (2S,3S,4R,5R,6S)-N-benzyl-3,4,5-tribenzyloxy-6-benzyloxymethyl-2-(2-propenyl)piperidine 

Relevant articles and documents

Synthesis, Conformational Analysis, and Complexation Study of an Iminosugar-Aza-Crown, a Sweet Chiral Cyclam Analog

A new family of chiral C2 symmetric tetraazamacrocycles, coined ISAC for IminoSugar Aza-Crown, incorporating two iminosugars adopting a 4C1 conformation is disclosed. Multinuclear NMR experiments on the corresponding Cdsu

Access to L-and D-iminosugar C-glycosides from a D-gluco-derived 6-azidolactol exploiting a ring isomerization/alkylation strategy

A flexible synthetic access to six-membered l- and d-iminosugar C-glycosides is reported starting from the easily available 6-azido-6-deoxy-2,3, 4-tri-O-benzyl-d-glucopyranose precursor. This methodology involves a highly diastereoselective tandem ring enlargement/alkylation and a stereocontrolled ring contraction. It allows an efficient synthesis of iminosugar C-glycosides displaying structural diversity at both C-1 and C-6.