1355020-66-4Relevant articles and documents
Cp?Co(III)-catalyzed oxidative C-H alkenylation of benzamides with ethyl acrylate
Suzuki, Yudai,Sun, Bo,Yoshino, Tatsuhiko,Kanai, Motomu,Matsunaga, Shigeki
supporting information, p. 4552 - 4556 (2015/06/08)
The utility of Cp?Co(III)-catalysts was expanded to oxidative C-C bond-forming reaction. In situ-generated Cp?Co(III)-catalyst, rather than a preformed cationic Cp?Co(III)-complex, was effective. Oxidative alkenylation of benzamides and acetanilide with ethyl acrylate proceeded with silver acetate as a stoichiometric oxidant, giving products in up to 93% yield.