1355020-72-2Relevant academic research and scientific papers
Ruthenium-catalyzed oxidative C - H alkenylations of anilides and benzamides in water
Ackermann, Lutz,Wang, Lianhui,Wolfram, Ratnakancana,Lygin, Alexander V.
supporting information; experimental part, p. 728 - 731 (2012/03/22)
A cationic ruthenium(II) complex enabled efficient oxidative alkenylations of anilides in water as a green solvent and proved applicable to double C - H bond functionalizations of (hetero)aromatic amides with ample scope. Detailed studies provided strong support for a change of ruthenation mechanism in the two transformations, with an irreversible metalation as the key step in cross-dehydrogenative alkenylations of benzamides.
