1355061-76-5

Basic information

• Product Name: C₁₁H₁₂FNO₂
• Synonyms: C₁₁H₁₂FNO₂
• CAS NO: 1355061-76-5
• Molecular Weight: 209.22
• Mol File: 1355061-76-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₂FNO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₂FNO₂(1355061-76-5)
• EPA Substance Registry System: C₁₁H₁₂FNO₂(1355061-76-5)

Safety Data

• Hazardous Substances Data: 1355061-76-5(Hazardous Substances Data)

Upstream product

• 459-57-4 4-fluorobenzaldehyde 
• 459-32-5 4-fluorocinnamic acid 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 

Downstream Products

• 1422176-90-6 (1S,2S,3S)-2-(4-fluorophenyl)-3-fluoro-N-methoxy-N-methyl-cyclopropanecarboxamide 
• 1455028-46-2 (1S,2S)-2-(4-fluorophenyl)-N-methoxy-N-methylcyclopropanecarboxamide 
• 372183-93-2 2-(4-fluorophenyl)cyclopropane-1-carbaldehyde 

Relevant articles and documents

Radical-Cation Vinylcyclopropane Rearrangements by TiO2Photocatalysis

Radical cation vinylcyclopropane rearrangements by TiO2 photocatalysis in lithium perchlorate/nitromethane solution are described. The reactions are triggered by oxidative single electron transfer, which is followed by immediate ring-opening of the cyclopropanes to generate distonic radical cations as unique reactive intermediates. This approach can also be applied to vinylcyclobutane, leading to the construction of six-membered rings. A stepwise mechanism via distonic radical cations is proposed based on preliminary mechanistic studies, which is supported by density functional theory calculations.