1355700-52-5Relevant academic research and scientific papers
Radical-mediated sulfonyl alkynylation, allylation, and cyanation of propellane
Wu, Zhen,Xu, Yaohui,Zhang, Huihui,Wu, Xinxin,Zhu, Chen
supporting information, p. 6066 - 6069 (2021/06/21)
Bicyclo[1.1.1]pentane (BCP) is widely applied as the bioisostere for aryl, internal alkynes, andtert-butyl groups in medicinal chemistry. We herein disclose an efficient and practical preparation of sulfonyl alkynyl/allyl/cyano-substituted BCP derivatives
Accessing the Rare Diazacyclobutene Motif
Narangoda, Chandima J.,Lex, Timothy R.,Moore, Madelyn A.,McMillen, Colin D.,Kitaygorodskiy, Alex,Jackson, James E.,Whitehead, Daniel C.
supporting information, p. 8009 - 8013 (2019/01/04)
A formal [2 + 2] cycloaddition of 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) with electron-rich alkynyl sulfides and selenides is described. These investigations provide a convenient method to access diazacyclobutenes in good yield while tolerating a rela
A one-pot synthesis of alkynyl sulfides from terminal alkynes
Zheng, Weixin,Zheng, Fenfen,Hong, Ya,Hu, Linfeng
experimental part, p. 105 - 110 (2012/03/26)
A one-pot synthesis of alkynyl sulfide from terminal alkyne has been reported via lithiation of the alkyne, oxidative addition of sulfur, consecutively followed by the nucleophilic substitution of lithium alkynyl thiolate to various halides.
