70856-93-8Relevant academic research and scientific papers
Stereoselective hydrozirconation of alkynylsulfide and regioselective synthesis of haloalkenyl sulfide via electrophile-switched halogenation of thioalkenyl zirconocene
Zheng, Weixin,Hong, Ya,Wang, Ping,Zheng, Fenfen,Zhang, Yanjing,Wang, Wei
supporting information, p. 3643 - 3646 (2013/07/19)
Stereoselective preparation of alkenyl sulfide was carried out via syn-hydrozirconation of the alkynyl sulfide. Regiochemistry of halogenation of the thioalkenyl zirconocene could be switched by different halides. α-Chloroalkenyl sulfide or β-haloalkenyl
Straightforward and highly efficient catalyst-free regioselective reaction of thiol to β-nitrostyrene: a concise synthesis of vinyl sulfide and nitro sulfide
Chu, Cheng-Ming,Tu, Zhijay,Wu, Pohsi,Wang, Chieh-Chieh,Liu, Ju-Tsung,Kuo, Chun-Wei,Shin, Yu-Hsuan,Yao, Ching-Fa
scheme or table, p. 3878 - 3885 (2009/09/30)
Under catalyst-free reaction conditions, solvent-mediated addition of thiol 2 to β-nitrostyrene 1 proceeded with regioselective control to afford either adduct 3 or vinyl sulfide 4 in good to excellent yield. Thermodynamic and autocatalytic reaction mecha
Peculiar Aspects of the Anodic Oxidation of Vinylic Sulfides
Guillanton, Georges Le,Simonet, Jacques
, p. 437 - 444 (2007/10/02)
In the anodic oxidation of vinylic sulfides on platinum in acetonitrile, a non-classical sulfonium ion explains satisfactorily the transfer of the thioether group leading to an aldehyde in the presence of water, or its acetal in the presence of methanol.Some other reactions depend on the structure of the substrate, particularly the dimerization into anodically inactive forms likely to decompose during the work-up, to lead in some cases to masked ketenes having the structure of a gem-disulfide.
