1355722-23-4

Basic information

• Product Name: 1-(pentafluoroethyl)-4-(trimethylsilyl)benzene
• Synonyms: 1-(pentafluoroethyl)-4-(trimethylsilyl)benzene
• CAS NO: 1355722-23-4
• Molecular Weight: 268.302
• Mol File: 1355722-23-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(pentafluoroethyl)-4-(trimethylsilyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(pentafluoroethyl)-4-(trimethylsilyl)benzene(1355722-23-4)
• EPA Substance Registry System: 1-(pentafluoroethyl)-4-(trimethylsilyl)benzene(1355722-23-4)

Safety Data

• Hazardous Substances Data: 1355722-23-4(Hazardous Substances Data)

Upstream product

• 17881-56-0 1-iodo-4-(trimethylsilyl)benzene 
• 75-77-4 chloro-trimethyl-silane 
• 118559-17-4 1-chloro-4-(pentafluoroethyl)benzene 

Relevant articles and documents

A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate

A method for the copper-catalyzed pentafluoroethylation of aryl iodides using potassium (pentafluoroethyl)trimethoxyborate has been developed. The borate was found to be a convenient pentafluoroethyl source. In parallel, it was found that the solvent, as well as ligand, makes significant impact on the catalytic perfluoroalkylations.

Cu-deposits on Mg metal surfaces promote electron transfer reactions

The enhancement of the electron transfer processes in the Grignard reagent formation-type ring silylation and the defluorination-silylation of perfluoroalkyl benzenes by Cu(0)-deposited Mg metal were confirmed. Microscopic analysis and substituent effects implied a different reduction process in the presence of Cu-deposited Mg metal than in the presence of bare Mg metal.