17881-56-0Relevant articles and documents
Prediction of perception: Probing the hOR17-4 olfactory receptor model with silicon analogues of bourgeonal and lilial
Doszczak, Leszek,Kraft, Philip,Weber, Hans-Peter,Bertermann, Ruediger,Triller, Annika,Hatt, Hanns,Tacke, Reinhold
, p. 3367 - 3371 (2007)
(Figure Presented) Sense and sensibility: Silicon analogues of the lily-of-the-valley odorants lilial and bourgeonal demonstrate that the electronic surface structure determines the interaction of an odorant with its olfactory receptor. The subtle changes
Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation
Harper, Matthew J.,Emmett, Edward J.,Bower, John F.,Russell, Christopher A.
supporting information, p. 12386 - 12389 (2017/09/22)
Under the conditions of oxidative gold catalysis, exposure of ethylene to aryl silanes and alcohols generates products of 1,2-oxyarylation. This provides a rare example of a process that allows catalytic differential 1,2-difunctionalization of this feedstock chemical.
Further studies on the iodination of aryltrimethylsilanes
Jacob,Chen,Stec
, p. 611 - 614 (2007/10/02)
Aryltrimethylsilanes can be readily iodinated using iodine monochloride and a silver salt in methanol. This procedure works well with aromatic rings that contain a deactivating group and is compatible with sensitive functional groups. To illustrate this a carbobenzyloxy protected 4-trimethylsilylphenylalanine ester was iodinated in good yield. The use of iodine monochloride instead of iodine results in faster reaction times than previously reported and reduced the waste of iodine, which would be beneficial in procedures where the use of other isotopes of iodine would be desired. Careful choice of solvents also allows the monoiodination of 1,4-bis(trimethylsilyl)benzene in good yield, which could prove useful in the synthesis of novel arylsilanes.
