135579-83-8

Basic information

• Product Name: 6-CHLOROHEXYLZINC BROMIDE
• Synonyms: 6-CHLOROHEXYLZINC BROMIDE;6-CHLOROHEXYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;6-chlorohexylzinc bromide solution;Bromo-(6-chlorohexyl)-zinc;2-Acrylamidophenylboronic acid pinacol ester;Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) proprionate;6-Chlorohexylzinc bromide solution 0.5 in THF;6-Chlorohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
• CAS NO: 135579-83-8
• Molecular Formula: C₆H₁₂BrClZn
• Molecular Weight: 264.91
• Product Categories: Alkyl;Organoborons;Organozinc Halides;Reike and Organozinc Reagents
• Mol File: 135579-83-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: 1 °F
• Appearance: /
• Density: 0.974 g/mL at 25 °C
• Vapor Pressure: 10.2mmHg at 25°C
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 6-CHLOROHEXYLZINC BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-CHLOROHEXYLZINC BROMIDE(135579-83-8)
• EPA Substance Registry System: 6-CHLOROHEXYLZINC BROMIDE(135579-83-8)

Safety Data

• Hazard Codes: F,Xn
• Statements: 14-19-22-36/38-40-36/37-11
• Safety Statements: 16-26-33-36-36/37
• RIDADR: UN 2056 3/PG 2
• WGK Germany: 1
• Hazardous Substances Data: 135579-83-8(Hazardous Substances Data)

Usage

General Description

6-Chlorohexylzinc bromide is a chemical compound with the formula C6H13ClZnBr, and it is used as a reagent in organic synthesis. It is a zinc organometallic compound that is commonly employed in cross-coupling reactions to form carbon-carbon bonds. 6-CHLOROHEXYLZINC BROMIDE is also used in the preparation of various organic compounds, particularly those containing carbon-carbon and carbon-heteroatom bonds. 6-Chlorohexylzinc bromide is a versatile and useful reagent in the field of organic chemistry due to its ability to participate in a wide range of reactions, making it a valuable tool for synthetic chemists in the production of pharmaceuticals, agrochemicals, and other fine chemicals.

InChI:InChI=1/C6H12Cl.BrH.Zn/c1-2-3-4-5-6-7;;/h1-6H2;1H;/q-1;;+2/p-1/rC6H12Cl.BrZn/c1-2-3-4-5-6-7;1-2/h1-6H2;/q-1;+1

Upstream product

• 6294-17-3 1-bromo-6-chlorohexane 
• 7440-66-6 zinc 

Downstream Products

• 1416254-68-6 1-cyclohexylnonan-4-yl 1-naphthoate 
• 143612-79-7 3-(4-chlorobutyl)-5-cyanoindole 
• 1365842-01-8 N-(8-chloro-2-phenyloctyl)-4-methylbenzenesulfonamide 
• 1314332-20-1 2-(1-(benzyloxy)-10-chlorodecan-2-yl)isoindoline-1,3-dione 

Relevant articles and documents

Preparation method of 5-cyano-3-(4-chlorobutyl)-benzpyrole

The invention belongs to the filed of chemical synthesis and discloses a preparation method of 5-cyano-3-(4-chlorobutyl)-benzpyrole. The method comprises the following steps: synthesizing 5-cyano-3-(4-chlorobutyl)-benzpyrole from 4-cyano phenyl diazoamino tetrafluoroborate as a raw material and a zinc reagent solution of 6-bromine chloride hexane under an acid condition. The 5-cyano-3-(4-chlorobutyl)-benzpyrole has the advantages of being high in yield, simple in process, green and environmental-friendly, and has very good industrialization prospect.

The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivatives

A palladium-catalyzed hydroalkylation reaction of protected allylic alcohols using alkylzinc bromide reagents is reported. This account includes numerous allylic, homoallylic, and bishomoallylic alcohol derivatives, all with a uniform selectivity of >20:1