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6-Chlorohexylzinc bromide, with the chemical formula C6H13ClZnBr, is a zinc organometallic compound that serves as a reagent in organic synthesis. It is known for its versatility in participating in a wide range of reactions, particularly cross-coupling reactions, to form carbon-carbon and carbon-heteroatom bonds. This makes 6-CHLOROHEXYLZINC BROMIDE a valuable tool for synthetic chemists in the production of pharmaceuticals, agrochemicals, and other fine chemicals.

135579-83-8

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135579-83-8 Usage

Uses

Used in Organic Synthesis:
6-CHLOROHEXYLZINC BROMIDE is used as a reagent for cross-coupling reactions to form carbon-carbon bonds, which is crucial in the synthesis of complex organic molecules.
Used in Pharmaceutical Industry:
6-CHLOROHEXYLZINC BROMIDE is used as a synthetic intermediate for the production of pharmaceuticals, contributing to the development of new drugs and therapeutic agents.
Used in Agrochemical Industry:
6-CHLOROHEXYLZINC BROMIDE is used as a precursor in the synthesis of agrochemicals, aiding in the creation of effective pesticides and other agricultural products.
Used in Fine Chemicals Production:
6-CHLOROHEXYLZINC BROMIDE is used as a key component in the synthesis of fine chemicals, which are essential in various industries such as fragrances, dyes, and specialty chemicals.

Check Digit Verification of cas no

The CAS Registry Mumber 135579-83-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,5,5,7 and 9 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 135579-83:
(8*1)+(7*3)+(6*5)+(5*5)+(4*7)+(3*9)+(2*8)+(1*3)=158
158 % 10 = 8
So 135579-83-8 is a valid CAS Registry Number.
InChI:InChI=1/C6H12Cl.BrH.Zn/c1-2-3-4-5-6-7;;/h1-6H2;1H;/q-1;;+2/p-1/rC6H12Cl.BrZn/c1-2-3-4-5-6-7;1-2/h1-6H2;/q-1;+1

135579-83-8 Well-known Company Product Price

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  • Aldrich

  • (497797)  6-Chlorohexylzincbromidesolution  0.5 M in THF

  • 135579-83-8

  • 497797-50ML

  • 1,634.49CNY

  • Detail

135579-83-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name bromozinc(1+),1-chlorohexane

1.2 Other means of identification

Product number -
Other names 1-chlorohexylZnBr

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:135579-83-8 SDS

135579-83-8Relevant academic research and scientific papers

Preparation method of 5-cyano-3-(4-chlorobutyl)-benzpyrole

-

Paragraph 0029-0034, (2017/09/01)

The invention belongs to the filed of chemical synthesis and discloses a preparation method of 5-cyano-3-(4-chlorobutyl)-benzpyrole. The method comprises the following steps: synthesizing 5-cyano-3-(4-chlorobutyl)-benzpyrole from 4-cyano phenyl diazoamino tetrafluoroborate as a raw material and a zinc reagent solution of 6-bromine chloride hexane under an acid condition. The 5-cyano-3-(4-chlorobutyl)-benzpyrole has the advantages of being high in yield, simple in process, green and environmental-friendly, and has very good industrialization prospect.

Electron-deficient olefin ligands enable generation of quaternary carbons by Ni-catalyzed cross-coupling

Huang, Chung-Yang,Doyle, Abigail G.

supporting information, p. 5638 - 5641 (2015/05/20)

A Ni-catalyzed Negishi cross-coupling with 1,1-disubstituted styrenyl aziridines has been developed. This method delivers valuable β-substituted phenethylamines via a challenging reductive elimination that affords a quaternary carbon. A novel electron-deficient olefin ligand, Fro-DO, proved crucial for achieving high rates and chemoselectivity for C-C bond formation over β-H elimination. This ligand is easy to access, is stable, and presents a modular framework for reaction discovery and optimization. We expect that these attributes, combined with the fact that the ligands impart distinct electronic properties to a metal, will support the invention of new transformations not previously possible using established ligands.

The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivatives

DeLuca, Ryan J.,Sigman, Matthew S.

supporting information, p. 92 - 95 (2013/03/28)

A palladium-catalyzed hydroalkylation reaction of protected allylic alcohols using alkylzinc bromide reagents is reported. This account includes numerous allylic, homoallylic, and bishomoallylic alcohol derivatives, all with a uniform selectivity of >20:1

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