135663-93-3

Basic information

• Product Name: (-)-1-phenyl-3,4-pentadien-2-ol
• CAS NO: 135663-93-3
• Molecular Weight: 160.216
• Mol File: 135663-93-3.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: (-)-1-phenyl-3,4-pentadien-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-1-phenyl-3,4-pentadien-2-ol(135663-93-3)
• EPA Substance Registry System: (-)-1-phenyl-3,4-pentadien-2-ol(135663-93-3)

Safety Data

• Hazardous Substances Data: 135663-93-3(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 135663-97-7 1-phenylbut-3-yn-2-ol 
• 108-05-4 vinyl acetate 
• 135663-93-3 1-phenyl-3,4-pentadien-2-ol 
• 122-78-1 phenylacetaldehyde 
• 14657-29-5 tetrapropadienyl stannane 
• 624-65-7 2-propynyl chloride 
• 18295-60-8 allenylmagnesium bromide 
• 106-96-7 propargyl bromide 

Downstream Products

• 127559-61-9 (-)-1-phenyl-3,4-pentadien-2-ol 
• 135664-04-9 Acetic acid (R)-1-benzyl-buta-2,3-dienyl ester 
• 135664-04-9 Acetic acid (S)-1-benzyl-buta-2,3-dienyl ester 
• 1344703-91-8 6,6,7,7,8,8,9,9,9-nonafluoro-4-iodo-1-phenyl-3(Z)-nonen-2-ol 
• 1361252-02-9 (R)-2-benzyl-2,5-dihydrofuran 
• 1388792-15-1 (S)-2-benzyl-2,5-dihydrofuran 
• 1361251-89-9 (S)-1-phenylpenta-3,4-dien-2-ol 
• 1039769-96-4 (S)-3-butyl-2-methyl-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 
• 1039769-91-9 2-butyl-3-phenyl-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 
• 1039769-77-1 3-butyl-2-phenyl-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 
• 1039769-89-5 3-(methoxycarbonyl)-2-pentyl-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 
• 1039769-75-9 3-butyl-2-methyl-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 
• 1039769-84-0 3-butyl-2-(o-chlorophenyl)-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 
• 1039769-81-7 3-butyl-2-(p-nitrophenyl)-4-(5'-phenyl-1',3'-pentadien-3'(E)-2'-yl)-2,5-dihydrofuran 

Relevant articles and documents

Cobalt-Catalyzed C8-Dienylation of Quinoline-N-Oxides

An efficient Cp*CoIII-catalyzed C8-dienylation of quinoline-N-oxides was achieved by employing allenes bearing leaving groups at the α-position as the dienylating agents. The reaction proceeds by CoIII-catalyzed C?H activation of qui

Highly stereoselective kinetic resolution of α-allenic alcohols: An enzymatic approach

A highly efficient lipase AK-catalyzed direct kinetic resolution of a variety of α-allenic alcohols was developed. With the complementary to previous studies, the current reaction system is effective on a broad range of substituents (R1) at C(1), such as alkyl, aryl, alkenyl, and alkynyl groups. The Jones-Burgess empirical model was modified to interpret the reversed selectivity during the acetylation of secondary alcohol. The methyl group at C(2) of allenic alcohols implied a small structural adjustment in the catalytic triad of lipase AK, representing a potential direction for future site-directed mutagenesis.

CuI-catalyzed synthesis of functionalized terminal allenes from 1-alkynes

Relative to our original protocol that uses CuI (0.5 equiv.), paraformaldehyde (2.5 equiv.), and dicyclohexylamine (1.8 equiv.), a facile and efficient protocol for the gram-scale synthesis of functionalized terminal allenes by using CuI (7.5-10 mol-%), p