1357175-54-2

Basic information

• Product Name: (E)-3-(4-chloropheny)-1-phenylpent-1-ene
• Synonyms: (E)-3-(4-chloropheny)-1-phenylpent-1-ene
• CAS NO: 1357175-54-2
• Molecular Weight: 256.775
• Mol File: 1357175-54-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-3-(4-chloropheny)-1-phenylpent-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-(4-chloropheny)-1-phenylpent-1-ene(1357175-54-2)
• EPA Substance Registry System: (E)-3-(4-chloropheny)-1-phenylpent-1-ene(1357175-54-2)

Safety Data

• Hazardous Substances Data: 1357175-54-2(Hazardous Substances Data)

Upstream product

• 1384458-53-0 (E)-5-phenylpent-4-en-2-yl 4-methylbenzenesulfonate 
• 1679-18-1 4-Chlorophenylboronic acid 
• 94421-30-4 (E)-1-phenyl-1-penten-3-ol acetate 
• 14644-80-5 sodium tetrakis(4-chlorophenyl)borate 

Relevant articles and documents

Pd(quinox)-catalyzed allylic relay Suzuki reactions of secondary homostyrenyl tosylates via alkene-assisted oxidative addition

Pd-catalyzed allylic relay Suzuki cross-coupling reactions of secondary alkyl tosylates, featuring a sterically-hindered oxidative addition and precise control of β-hydride elimination, are reported. The identification of a linear free energy relationship between the relative rates of substrate consumption and the electronic nature of the substrate alkene suggests that the oxidative addition requires direct alkene involvement. A study of the effect of alkyl chain length on the reaction outcome supports a chelation-controlled oxidative addition. This journal is the Partner Organisations 2014.