135733-96-9Relevant academic research and scientific papers
A carbene to biradical rearrangement: Reaction paths from (8-methyl-1-naphthyl)carbene to acenaphthene
Biewer, Michael C.,Platz, Matthew S.,Roth, Martin,Wirz, Jakob
, p. 8069 - 8073 (1991)
Photochemical nitrogen elimination from 1-(diazomethyl)-8-methylnaphthalene (2) yields acenaphthene (3) via the reactive intermediates (8-methyl-1-naphthyl)carbene (a) and 1,8-naphthoquinodimethane (b). The triplet biradical b was observed by absorption s
