Journal of the American Chemical Society p. 8069 - 8073 (1991)
Update date:2022-08-02
Topics:
Biewer, Michael C.
Platz, Matthew S.
Roth, Martin
Wirz, Jakob
Photochemical nitrogen elimination from 1-(diazomethyl)-8-methylnaphthalene (2) yields acenaphthene (3) via the reactive intermediates (8-methyl-1-naphthyl)carbene (a) and 1,8-naphthoquinodimethane (b). The triplet biradical b was observed by absorption s
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