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Synthesis of long-chain picolinic derivatives
Faivre, V.,Roizard, D.,Brembilla, A.,Lochon, P.
, p. 278 - 285 (2007/10/02)
5-Hydroxypicoline is the common starting product for the reported synthesis of new picolinic derivatives with various oxidation degrees (methyl, N-oxide, alcohol, aldehyde, acid) and with their 5-position substituted by a linear alkoxy chain with n carbon atoms (n = 3,5,7,10,12,15 and 18).The parent carboxylic acids are then converted into activated esters which can be used as substrates in micellar catalysis studies. --- Key words: 5-hydroxypicoline / O-alkylation / 5-alkoxypicolinic derivatives
