135799-64-3

Upstream product

• 135799-59-6 {(2R,3S)-3-[(R)-1-Methyl-2-(tetrahydro-pyran-2-yloxy)-ethyl]-oxiranyl}-methanol 
• 135799-58-5 (E)-(S)-4-Methyl-5-(tetrahydro-pyran-2-yloxy)-pent-2-en-1-ol 
• 135799-62-1 Benzoic acid (3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-5-(tetrahydro-pyran-2-yloxy)-pentyl ester 
• 135799-61-0 Benzoic acid (3R,4R)-3-hydroxy-4-methyl-5-(tetrahydro-pyran-2-yloxy)-pentyl ester 
• 135799-57-4 (E)-(S)-4-Methyl-5-(tetrahydro-pyran-2-yloxy)-pent-2-enoic acid methyl ester 
• 135799-60-9 (3R,4R)-4-Methyl-5-(tetrahydro-pyran-2-yloxy)-pentane-1,3-diol 
• 73992-01-5 (2S)-2-methyl-3-(tetrahydro-2H-pyran-2-oxy)propanal 
• 88557-53-3 (R)-2-Methyl-3-(tetrahydro-pyran-2-yloxy)-propionic acid methyl ester 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 100-39-0 benzyl bromide 
• 135799-63-2 (3R,4R)-3-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-5-(tetrahydro-pyran-2-yloxy)-pentan-1-ol 

Downstream Products

• 135799-65-4 (2R,3R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-pentan-1-ol 
• 135799-72-3 (2R,4R,5S,6R,7R)-9-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4-((E)-2-methoxymethoxy-vinyl)-2,6-dimethyl-nonane-1,5-diol 
• 135799-73-4 (2S,3R)-2-<(1R,2R)-4-(Benzyloxy)-2-<(tert-butyldimethylsilyl)oxy>-1-methylbutyl>-3-<(2R)-3-hydroxy-2-methylpropyl>-5-methoxy-1,2,3,4-tetrahydrofuran 
• 135799-66-5 (2S,3R)-5-(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-2-methylpentanal 

Relevant academic research and scientific papers

Highly Stereoselective SE' Additions of α-Alkoxy Allylstannanes to Chiral Aldehydes. Synthesis of a C-1-C-9 Subunit of Tylonolide

The racemic α-alkoxy allylic stannane RS4 adds to the 2S aldehyde 24 to afford the homoaldol adduct 25 (45percent) derived exclusively from the S enantiomer S4 along with isomerized (R)-γ-alkoxy allylstannane 26 of >80percentee (50percent) and unreacted a