135799-66-5Relevant academic research and scientific papers
Total Synthesis, Stereochemical Revision, and Biological Reassessment of MandelalideA: Chemical Mimicry of Intrafamily Relationships
Willwacher, Jens,Heggen, Berit,Wirtz, Conny,Thiel, Walter,Fürstner, Alois
supporting information, p. 10416 - 10430 (2015/07/07)
MandelalideA and three congeners had recently been isolated as the supposedly highly cytotoxic principles of an ascidian collected off the South African coastline. Since these compounds are hardly available from the natural source, a concise synthesis rou
Total syntheses of 28,29-diepi-arenamide A, 29-epi-arenamide A, and 28-epi-arenamide A
Jithender Reddy, V.,Pradhan, Tapan Kumar,Ghosh, Subhash
, p. 6148 - 6150,3 (2020/08/20)
This communication describes the synthesis of stereochemical analogs of arenamide A, a 19-membered cytotoxic depsipeptide isolated from the fermentation broth of a marine bacterial strain Salinispora arenicola. The key steps are diastereoselective aldol r
Highly Stereoselective SE' Additions of α-Alkoxy Allylstannanes to Chiral Aldehydes. Synthesis of a C-1-C-9 Subunit of Tylonolide
Marshall, James A.,Yashunsky, Dmitry V.
, p. 5493 - 5495 (2007/10/02)
The racemic α-alkoxy allylic stannane RS4 adds to the 2S aldehyde 24 to afford the homoaldol adduct 25 (45percent) derived exclusively from the S enantiomer S4 along with isomerized (R)-γ-alkoxy allylstannane 26 of >80percentee (50percent) and unreacted a
