135886-84-9Relevant academic research and scientific papers
The Combination of Benzaldehyde and Nickel-Catalyzed Photoredox C(sp3)?H Alkylation/Arylation
Zhang, Lumin,Si, Xiaojia,Yang, Yangyang,Zimmer, Marc,Witzel, Sina,Sekine, Kohei,Rudolph, Matthias,Hashmi, A. Stephen K.
, p. 1823 - 1827 (2019)
Herein we report a highly selective photoredox C(sp3)?H alkylation/arylation of ethers through the combination of a photo-organocatalyst (benzaldehyde) and a transition-metal catalyst (nickel). This method provides a simple and general strategy for the C(sp3)?H alkylation/arylation of ethers. A selective late-stage modification of (?)-ambroxide has also been conducted to demonstrate the applicability of the method.
Convenient preparations of t-butyl esters and ethers from t-butanol
Wright, Stephen W.,Hageman, David L.,Wright, Ann S.,McClure, Lester D.
, p. 7345 - 7348 (2007/10/03)
A one-pot preparation of t-butyl esters and ethers is described that proceeds from the carboxylic acid or alcohol and t-butanol using only anhydrous magnesium sulfate and catalytic sulfuric acid as additional reagents. The method affords t-butyl esters and ethers in good yields and is applicable to a variety of substrates.
Hydrogenolysis and One-Electron Reduction of Alkoxy Sulfones
Julia, Marc,Uguen, Daniel,Zhang, Da
, p. 279 - 290 (2007/10/02)
The readily available 1-t-butoxyalkyl sulfones were converted by hydride reduction into alkyl t-butyl ethers.Reductive coupling with sodium metal or amalgam in an aprotic solvent led to glycol bis-1,2-O-t-butyl ethers.Polyethers such as 18-crown-6 can be synthesized by this procedure.
