1360059-02-4

Basic information

• Product Name: Li(O(C₂H₅)2)3⁽¹⁺⁾*Al((CH₃)2Si(NC₆H₅)2)2^(1-)*C₆H₅CH₃=[Li(O(C₂H₅)2)3][Al((CH₃)2Si(NC₆H₅)2)2]*C₆H₅CH₃
• CAS NO: 1360059-02-4
• Molecular Weight: 829.191
• Mol File: 1360059-02-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Li(O(C₂H₅)2)3⁽¹⁺⁾*Al((CH₃)2Si(NC₆H₅)2)2^(1-)*C₆H₅CH₃=[Li(O(C₂H₅)2)3][Al((CH₃)2Si(NC₆H₅)2)2]*C₆H₅CH₃(CAS DataBase Reference)
• NIST Chemistry Reference: Li(O(C₂H₅)2)3⁽¹⁺⁾*Al((CH₃)2Si(NC₆H₅)2)2^(1-)*C₆H₅CH₃=[Li(O(C₂H₅)2)3][Al((CH₃)2Si(NC₆H₅)2)2]*C₆H₅CH₃(1360059-02-4)
• EPA Substance Registry System: Li(O(C₂H₅)2)3⁽¹⁺⁾*Al((CH₃)2Si(NC₆H₅)2)2^(1-)*C₆H₅CH₃=[Li(O(C₂H₅)2)3][Al((CH₃)2Si(NC₆H₅)2)2]*C₆H₅CH₃(1360059-02-4)

Safety Data

• Hazardous Substances Data: 1360059-02-4(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 7446-70-0 aluminium trichloride 
• 60-29-7 diethyl ether 
• 13435-09-1 Bis(anilino)dimethylsilane 
• 108-88-3 toluene 

Relevant articles and documents

Synthesis and crystal structures of aluminum, gallium and indium complexes with chelating Me2Si(NPh)22- ligands

The reaction of ECl3 (E = Al, Ga) with two equivalentsof Li 2Me2Si(NPh)2 (in diethyl ether/n-hexane) leads to the formation of bis-chelate complexes [Li(OEt2) 3][E{Me2Si(NPh)2}2] (E = Al (1), Ga (2)). Compounds 1 and 2 crystallize isotypically in the monoclinic system with a = 1136.42(6), b = 3267.9(1), c = 1360.37(8) pm, β = 94.320(7)° for 1 and a = 1140.88(6), b = 3261.7(2), c = 1360.20(8) pm, β = 94.641(7)° for 2. Both the compounds display a distorted tetrahedral coordination of the central metal atom to give a spirocyclic EN4Si2 core. The Al-N bond lengths are in the range of186.5-186.9 pm and for the Ga-N distances values between 192.3and 193.1 pm are observed. Treatment of InCl3 with three equivalents of Li2Me2Si(NPh)2 yields the tris-chelate [{Li(OEt2)}3In{Me2Si(NPh 2)}3] 3. Compound 3 crystallizes in the trigonal crystal system, space group R3c with a = 1852.4(1), and c = 3300.2(2) pm. The central indium atom is coordinated by threeMe2Si(NPh) 22- ligands in a distorted octahedral arrangement withIn-N bond lengths of 230.8 pm. Copyright