13604-13-2Relevant articles and documents
Controlled Synthesis of Thiazole-Based Polymers and Block Copolymers by RAFT Polymerization of Azolyl S-Vinyl Sulfides and Metal Complexation
Nakabayashi, Kazuhiro,Matsumura, Aiko,Abiko, Yohei,Mori, Hideharu
, p. 1616 - 1629 (2016)
We studied the RAFT polymerization of five S-vinyl sulfide derivatives containing azole units, including 2-benzothiazolyl vinyl sulfide (BTVS), 2-thiazolyl vinyl sulfide (2-TVS), 1,3,4-thiadiazolyl vinyl sulfide (1,3,4-TVS), 5-methyl-1,3,4-thiadiazolyl vi
Synthesis of alkylthio- and arylthioheteroarenes by regioselective grignard reaction of thiocyanatoheteroarenes
Nagasaki, Izuru,Matsumoto, Miyuki,Yamashita, Masanori,Miyashita, Akira
, p. 1015 - 1024 (2007/10/03)
Treatment of thiocyanatoheteroarenes (1) with Grignard reagents (2) afforded alkylthio- or arylthioheteroarenes (3-6) in good yields. Grignard reagents regioselectively attacked the sulfur atom of the thiocyanato group owing to the metal-chelating effect of this group in combination with the hetero ring-nitrogen. 2-Thiocyanatopyridine (1a), 2-thiocyanatopyrimidine (1b), 2-thiocyanatobenzothiazole (1c), and 4-thiocyanatoquinazoline (1d) were converted into a variety of sulfides. Sulfides consisting of two heteroarenes linked by a sulfur atom were readily obtained by this method.
GAS/SOLID-REACTIONS WITH SULFUR COMPOUNDS
Kaupp, Gerd,Luebben, Doris,Sauerland, Olaf
, p. 109 - 120 (2007/10/02)
The various types of gas/solid-reactions (addition, elimination, substitution, condensation, catalyzed cycloaddition) in different branches of sulfur chemistry (heterocycles, S-vinyl-compounds, thioethers, thiols, sulfur dioxide) are reviewed, new types a