13604-13-2

Usage

InChI:InChI=1/C9H7NS2/c1-2-11-9-10-7-5-3-4-6-8(7)12-9/h2-6H,1H2

Upstream product

• 149-30-4 2-thioxo-3H-1,3-benzothiazole 
• 74-86-2 acetylene 
• 60372-29-4 2-(2-chloroethylsulfenyl)benzo[d][1,3]thiazole 
• 149-30-4 2-Mercaptobenzothiazole 
• 6011-99-0 benzo[d]thiazol-2-yl thiocyanate 
• 1826-67-1 vinyl magnesium bromide 
• 107-04-0 1-Bromo-2-chloroethane 
• 106-93-4 ethylene dibromide 

Downstream Products

• 13604-14-3 2-(2-tert-Butylmercapto-aethylmercapto)-benzthiazol 
• 13604-15-4 2-(2-phenylsulfanyl-ethylsulfanyl)-benzothiazole 
• 13604-19-8 Benzthiazolyl-(2)-vinyl-sulfoxid 
• 2591-09-5 2-vinylsulfonylbenzo[d][1,3]thiazole 
• 13604-33-6 2-(2-phenylmethanesulfonyl-ethanesulfonyl)-benzothiazole 
• 13604-32-5 2-(2-benzenesulfonyl-ethanesulfonyl)-benzothiazole 
• 13604-31-4 2-(2-phenylmethanesulfinyl-ethanesulfonyl)-benzothiazole 
• 13604-24-5 2-(2-phenylsulfanyl-ethanesulfonyl)-benzothiazole 
• 13604-16-5 2-(2-Benzylmercapto-aethylmercapto)-benzthiazol 
• 29840-87-7 2-(2-Aethylmercapto-aethylmercapto)-benzthiazol 

Relevant academic research and scientific papers

Controlled Synthesis of Thiazole-Based Polymers and Block Copolymers by RAFT Polymerization of Azolyl S-Vinyl Sulfides and Metal Complexation

We studied the RAFT polymerization of five S-vinyl sulfide derivatives containing azole units, including 2-benzothiazolyl vinyl sulfide (BTVS), 2-thiazolyl vinyl sulfide (2-TVS), 1,3,4-thiadiazolyl vinyl sulfide (1,3,4-TVS), 5-methyl-1,3,4-thiadiazolyl vi

Synthesis of N- and S-vinyl derivatives of heteroaromatic compounds using phase-transfer catalysis

A method has been developed for the synthesis of N- and S-vinyl derivatives of heteroaromatic compounds from NH heterocycles or their thiols in the phase-transfer catalytic system ClCH2CH2Br-KOH (s)-18-crown-6-toluene. It is shown that it is possible to prepare N,S-divinyl derivatives of 3-mercaptoindole and 2-mercaptobenzimidazole.

Synthesis of alkylthio- and arylthioheteroarenes by regioselective grignard reaction of thiocyanatoheteroarenes

Treatment of thiocyanatoheteroarenes (1) with Grignard reagents (2) afforded alkylthio- or arylthioheteroarenes (3-6) in good yields. Grignard reagents regioselectively attacked the sulfur atom of the thiocyanato group owing to the metal-chelating effect of this group in combination with the hetero ring-nitrogen. 2-Thiocyanatopyridine (1a), 2-thiocyanatopyrimidine (1b), 2-thiocyanatobenzothiazole (1c), and 4-thiocyanatoquinazoline (1d) were converted into a variety of sulfides. Sulfides consisting of two heteroarenes linked by a sulfur atom were readily obtained by this method.

REACTIONS OF BENZOTHIAZOL-2-THIONE AND BENZOTHIAZOL-2-ONE WITH ACETYLENE

Reaction of benzothiazol-2-thione and benzothiazol-2-one with acetylene in the presence of potassium hydroxide or cadmium acetate gives 2-vinylthiobenzothiazole and 3-vinylbenzothiazol-2-one, respectively.Benzothiazol-2-thione is partially converted to benzothiazol-2-one by the action of Cd(OAc)2.Under vinylation conditions the latter also forms 2-vinylthioaniline.

GAS/SOLID-REACTIONS WITH SULFUR COMPOUNDS

The various types of gas/solid-reactions (addition, elimination, substitution, condensation, catalyzed cycloaddition) in different branches of sulfur chemistry (heterocycles, S-vinyl-compounds, thioethers, thiols, sulfur dioxide) are reviewed, new types a