13604-51-8

Upstream product

• 39536-32-8 sodium benzamidate 
• 2524-06-3 O,O-diisopropyl chlorothiophosphate 
• 28167-42-2 O,O'-diisopropyl amidophosphorothioate 
• 98-88-4 benzoyl chloride 
• 246021-18-1 O[AuP(C₆H₅)3]3⁽¹⁺⁾*ClO₄^(1-)=O[AuP(C₆H₅)3]3ClO₄ 
• 66078-55-5 N-(diisopropoxythiophosphoryl)thiobenzamide 
• 131746-39-9 sodium salt of N-diisopropoxythiophosphorylbenzamide 

Downstream Products

• 128342-59-6 potassium N-diisopropoxythiophosphorylbenzamidate 
• 131746-39-9 sodium salt of N-diisopropoxythiophosphorylbenzamide 
• 140693-32-9 Hg{C₆H₅C(O)NP(S)(OCH(CH₃)2)2}2 
• 128342-63-2 N-benzoyl-S-methyl-O,O-diisopropylmonophosphazene 
• 71039-21-9 N-diisopropoxyphosphorylthiobenzamide 

Relevant academic research and scientific papers

Gold and Silver Complexes with the Ligands N-[Bis(isopropoxy)-thiophosphoryl]thiobenzamide and N-[Bis(isopropoxy)thiophosphoryl]-N′-phenylthiourea

Gold and silver complexes with the N-[bis(isopropoxy)-thiophosphoryl]thiobenzamide (HL1) and N-[bis(isopropoxy)-thiophosphoryl]-N′-phenylthiourea (HL2) ligands are reported, The compounds [M(HL)(PPh3)]TfO, [Ag(HL)(TfO)] and [Ag(HL)(PPh3)2]TfO were obtained by the reaction of both ligands with the corresponding trifluoromethanesulfonate salts. The (acetylacetonato)gold and -silver materials [M(acac)(PPh3)] or [Au(acac)(C6F5)2] cause deprotonation of the ligands and afford [ML(PPh3)] or [AuL(C6F 5)2], whereas the reaction of [Au(TfO)(PPh3)] with HL1 in a 2:1 molar ratio in KOH/MeOH affords [Au 2(L1)(PPh3)2]TfO, The first homoleptic anionic metal compounds [AuIL2]- are also reported. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

REACTIONS OF N-PHOSPHORYLATED AMIDES AND THIOAMIDES WITH ALKYL HALIDES

N-Phosphorylated thioamides and also their alkali-metal salts are easily alkylated by alkyl halides at the sulfur atom of the thiocarbonyl group, and in this process the reactivities of the alkyl halides decrease in the sequence: primary>secondary>tertiary. N-Phosphorylated amides do not react with alkyl halides, whereas their alkali-metal salts form easily hydrolyzable products of alkylation at the sulfur or oxygen atom of the P=X group of the monophosphazene structure. Alkylation reactions of N-phosphorylated amides and thioamides take only one course: The formation of products of alkylation at the nitrogen atom is not observed.