2524-06-3Relevant articles and documents
Reactions of Phosphorylsulfenyl Chlorides with 2H-1,2,3-Diazaphospholes
Khusainova,Zyablikova,Reshetkova,Lamm,Cherkasov
, p. 1411 - 1413 (2007/10/03)
Formation of a quasiphosphonium salt in reaction of phosphorylsulfenyl chlorides with 1,2,3-diazaphospholes was established by dynamic 31P NMR spectroscopy. The salt is formed by addition of 2 mol of phosphorylsulfenyl chloride to the σ2λ3P=C endocyclic fragment by the 1,1- and 1,2-addition schemes. Decomposition of the salt yields mainly O,O-dialkyl phosphothiochloridate and, to a lesser extent, dialkyl phosphochloridate.
SYNTHESIS OF 10-(N'-PHENYL)IMIDOYL DERIVATIVES OF PHENOTHIAZINE, AND THEIR REACTIONS WITH O,O-DIALKYLTHIO- AND DITHIOPHOSPHATES
Kamalov, R. M.,Makarov, G. M.,Yarmukhametova, D. Kh.,Pudovik, M. A.,Cherkasov, R. A.,Pudovik, A. N.
, p. 2382 - 2388 (2007/10/02)
Condensation of phenothiazine with phenyl isocyanide dichloride has given 10-(N'-phenylchloroformimidoyl)phenothiazine, exchange reactions of which with salts of dialkylthio- and dithiophosphoric acids result in rearrangement of the initially formed 10-phenothiazines to 10-thiocarbamoyl>phenothiazines, while reaction with diisopropyl dithiophosphoric acid affords diisopropyl chlorothiophosphate, phenyl isothiocyanate, and phenothiazine. 10-(N'-Phenylethoxyformimidoyl)phenothiazine alkylates dithiophosphoric acid to give 10-(N'-phenylcarbamoyl)phenothiazine, while N2-phenyl-N1,N1-diethyl-(10-phenothiazinyl)formamidine reacts with diisopropyl dithiophosphoric acid, affording the salt N2-phenyl-N1,N1-diethyl-(10-phenothiazinyl)formamidinium O,O-diisopropyl dithiophosphate.
REACTION OF O,O-DIALKYL DITHIOPHOSPHATES WITH CHLOROSULFENYL ISOCYANIDE DICHLORIDE
Kamalov, R. M.,Makarov, G. M.,Zimin, M. G.,Cherkasov, R. A.,Pudovik, A. N.
, p. 202 - 203 (2007/10/02)
-