136052-84-1Relevant academic research and scientific papers
A combined transition-metal-catalyzed and photopromoted process: Synthesis of 2,3-fused 4-phenylnaphthalen-1-yl carboxylates from 1,7-diaryl-1,6-diynes
Yamamoto, Yoshihiko,Mori, Shota,Shibuya, Masatoshi
, p. 9093 - 9100 (2015)
2,3-Fused 4-phenylnaphthalen-1-yl carboxylates were synthesized in a step- and atom-economical manner using a ruthenium-catalyzed hydrocarboxylative cyclization of 1,7-diaryl-1,6-diynes and subsequent oxidative photocyclization. The scope of this novel two-step process was demonstrated by the construction of diverse structures from substrates with various tethers and terminal aryl groups. Late-stage C-H functionalizations of the arylnaphthalene product further enhance the synthetic potential of the developed process. Light a fuse! 2,3-Fused 4-phenylnaphthalen-1-yl carboxylates were synthesized in a step- and atom-economical manner using a ruthenium-catalyzed hydrocarboxylative cyclization of 1,7-diaryl-1,6-diynes and subsequent oxidative photocyclization. Late-stage C-H functionalizations of the obtained arylnaphthol derivatives further enhance the synthetic potential of the developed process (see scheme).
Ruthenium-catalyzed transfer oxygenative cyclization of α,ω-diynes: Unprecedented [2 + 2 + 1] route to bicyclic furans via ruthenacyclopentatriene
Yamashita, Ken,Yamamoto, Yoshihiko,Nishiyama, Hisao
supporting information; scheme or table, p. 7660 - 7663 (2012/06/30)
A novel oxygen-atom-transfer process enables the catalytic [2 + 2 + 1] synthesis of bicyclic furans from α,ω-diynes with DMSO. [CpRu(AN)3]PF6 catalyzed the transfer oxygenative cyclization of diynes with aryl terminal groups, while t
