136074-26-5

Basic information

• Product Name: bis(4-(allyloxy)phenyl)methanone
• Synonyms: bis(4-(allyloxy)phenyl)methanone
• CAS NO: 136074-26-5
• Molecular Weight: 294.35
• Mol File: 136074-26-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: bis(4-(allyloxy)phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-(allyloxy)phenyl)methanone(136074-26-5)
• EPA Substance Registry System: bis(4-(allyloxy)phenyl)methanone(136074-26-5)

Safety Data

• Hazardous Substances Data: 136074-26-5(Hazardous Substances Data)

Upstream product

• 611-99-4 4,4'-Dihydroxybenzophenone 
• 288248-49-7 4,4'-di(3-bromo-1-propoxy)benzophenone 
• 79-37-8 oxalyl dichloride 
• 1248383-98-3 C₂₇H₂₇BiO₃ 
• 1248384-09-9 C₂₇H₂₇InO₃ 
• 106-95-6 allyl bromide 
• 556-56-9 allyl iodid 

Relevant articles and documents

Synthesis of main chain polymeric benzophenone photoinitiator via thiol-ene click chemistry and Its use in free radical polymerization

Main chain polymeric benzophenone photoinitiator (PBP) was synthesized by using "Thiol-ene Click Chemistry" and characterized with 1H NMR, FTIR, UV, and phosphorescence spectroscopies. PBP as a polymeric photoinitiator presented excellent absor

Expedient carbonylation of aryl halides in aqueous or neat condition

An expedient and versatile, microwave-assisted procedure for the carbonylation of aryl halides with boronic acids, alcohols or amines in water or under neat conditions has been developed. The reaction is catalyzed by fluorous, oxime-based palladacycle 1 that shows an excellent recyclable property and low levels of Pd leaching. To demonstrate the usefulness of the protocol, we applied it to the preparation of compounds of pharmaceutical interest, including a precursor of the reverse transcriptase inhibitor, niacin, benzocaine and butamben.

Fluorous oxime palladacycle: A precatalyst for carbon-carbon coupling reactions in aqueous and organic medium

To facilitate precatalyst recovery and reuse, we have developed a fluorous, oxime-based palladacycle 1 and demonstrated that it is a very efficient and versatile precatalyst for a wide range of carbon-carbon bond formation reactions (Suzuki-Miyaura, Sonogashira, Stille, Heck, Glaser-type, and Kumada) in either aqueous or organic medium under microwave irradiation. Palladacycle 1 could be recovered through F-SPE in various coupling reactions with recovery ranging from 84 to 95% for the first cycle. Inductively coupled plasma optical emission spectrometry (ICP-OES) analyses of the Pd content in the crude product from each class of transformation indicated extremely low levels of leaching and the palladacycle could be reused four to five times without significant loss of activity.