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1361146-90-8

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  • (3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

    Cas No: 1361146-90-8

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  • (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-di-i-propylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

    Cas No: 1361146-90-8

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1361146-90-8 Usage

Reaction

Chiral ligand used in a platinum-catalyzed, enantioselective terpene construction. Chiral ligand used in a platinum-catalyzed, diboration of aliphatic 1-alkenes. Regio- and stereoselective homologation of 1,2-bis(boronic esters): stereocontrolled synthesis of 1,3-diols. Synthesis of β-lactams by palladium(0)-catalyzed C(sp3)-H carbamoylation.

Check Digit Verification of cas no

The CAS Registry Mumber 1361146-90-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,6,1,1,4 and 6 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1361146-90:
(9*1)+(8*3)+(7*6)+(6*1)+(5*1)+(4*4)+(3*6)+(2*9)+(1*0)=138
138 % 10 = 8
So 1361146-90-8 is a valid CAS Registry Number.

1361146-90-8Downstream Products

1361146-90-8Relevant articles and documents

Synthesis of Two Key Fragments of the Complex Polyhalogenated Marine Meroterpenoid Azamerone

Schnell, Simon D.,Linden, Anthony,Gademann, Karl

, p. 1144 - 1147 (2019/05/16)

A concise route toward two advanced fragments in the context of the total synthesis of the unique natural product azamerone is reported. Key synthetic features include the enantioselective synthesis of an epoxysilane and its Lewis-acid-induced cyclization and the installation of the pyridazine ring via a formylation/condensation sequence. This route provides strategic insights into the chemistry of phthalazinediols, facilitating synthetic approaches toward this class of natural products.

Enantiomerically enriched tris(boronates): Readily accessible conjunctive reagents for asymmetric synthesis

Coombs, John R.,Zhang, Liang,Morken, James P.

supporting information, p. 16140 - 16143 (2015/01/09)

The catalytic enantioselective diboration of vinyl boronate esters furnishes chiral tris(boronates) in a selective fashion. Subsequent deborylative alkylation occurs in a diastereoselective fashion, both for intermolecular and intramolecular processes.

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