1361243-32-4Relevant academic research and scientific papers
Self-assembly, AIEE and mechanochromic properties of amphiphilic α-cyanostilbene derivatives
Ren, Yanming,Zhang, Ruilin,Yan, Chao,Wang, Tingyan,Cheng, Huifang,Cheng, Xiaohong
, p. 5253 - 5259 (2017)
A series of amphiphilic α-cyanostilbene derivatives consisting of an α-cyanostilbene rodlike core with lipophilic and flexible alkyl chains at one end and a polar glycerol group at the opposite end have been synthesized and investigated by polarizing micr
Self-assembly of taper- and wedge-shaped maleimide derivatives: Synthesis and structure-property relationship
Vinayakumara,Kumar, Sandeep,Prasad, S. Krishna,Adhikari, Airody Vasudeva
, p. 765 - 772 (2019/04/25)
Herein, we describe design and synthesis of five new amphiphilic systems, viz. 10b-c and 11a-c composed of maleimide at the focal point and alkoxy phenyl ring at the periphery. Their self-assembling behaviour was examined systematically by varying the length of hydrophobic part and aromatic core segment. Evidently, on increasing the aromatic core length, maleimide based amphiphiles relatively emerge as two distinct molecular structures, i.e. wedge- and tapered-shaped. The mesomorphic studies of the two series reveal that, tapered-shaped maleimide derivatives assemble into a smectic A phase with an interesting phasmidic arrangement, whereas the wedge-shaped molecules exclusively form a prospective supramolecular hexagonal columnar mesophase through the intermolecular hydrogen-bonding via maleimide head group. These self-assembled materials could demonstrate high-sensitivity towards various external stimuli.
Catenation of self-assembled nanorings
Yagai, Shiki,Goto, Yusaku,Karatsu, Takashi,Kitamura, Akihide,Kikkawa, Yoshihiro
supporting information; experimental part, p. 13657 - 13660 (2012/01/13)
Till death do us part: Catenation of toroidal nanostructures (nanorings), self-assembled from more than 1000 small molecular building blocks in solution, occurs when aggregation takes place under high solution concentrations. The formation of interlocked
