Cas 1361252-01-8,(S)-2-(o-tolyl)-2,5-dihydrofuran

1361252-01-8

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Basic information

Product Name: (S)-2-(o-tolyl)-2,5-dihydrofuran
Synonyms: (S)-2-(o-tolyl)-2,5-dihydrofuran
CAS NO:1361252-01-8
Molecular Formula:
Molecular Weight: 160.216
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (S)-2-(o-tolyl)-2,5-dihydrofuran(CAS DataBase Reference)
NIST Chemistry Reference: (S)-2-(o-tolyl)-2,5-dihydrofuran(1361252-01-8)
EPA Substance Registry System: (S)-2-(o-tolyl)-2,5-dihydrofuran(1361252-01-8)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 1361252-01-8(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 1361252-01-8 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,6,1,2,5 and 2 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1361252-01:
(9*1)+(8*3)+(7*6)+(6*1)+(5*2)+(4*5)+(3*2)+(2*0)+(1*1)=118
118 % 10 = 8
So 1361252-01-8 is a valid CAS Registry Number.

1361252-01-8Upstream product

1361252-01-8Downstream Products

1361252-01-8Relevant academic research and scientific papers

SPIRO-1,1'-BIINDANE-7,7-BISPHOSPHINE OXIDES AS HIGHLY ACTIVE SUPPORTING LIGANDS FOR PALLADIUM-CATALYZED ASYMMETRIC HECK REACTION

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Page/Page column 37, (2015/01/06)

The present invention relates to catalyst complexes comprising palladium (Pd) and at least one spiro-1,1 '-biindane-7,7'- bisphosphine oxide ligand as disclosed herein, and their use. The present invention is further directed to the asymmetric Pd-catalyzed covalent carbon-carbon single bond formation from aryl, heteroaryl and alkenyl triflates and halides and olefins utilising the said catalyst complexes.

Asymmetric intermolecular heck reaction of aryl halides

Wu, Chunlin,Zhou, Jianrong

supporting information, p. 650 - 652 (2014/02/14)

The asymmetric intermolecular Heck reaction has been limited to aryl and vinyl triflates. Herein, we extend the reaction to aryl and vinyl bromides. Various cyclic olefins coupled with high enantioselectivity. Only bisphosphine oxides on a spiro backbone formed highly stereoselective Pd catalysts. The use of alcoholic solvents and alkylammonium salts were essential to promote halide dissociation from neutral arylpalladium complexes.

Highly active catalysts of bisphosphine oxides for asymmetric Heck reaction

Hu, Jian,Lu, Yunpeng,Li, Yongxin,Zhou, Jianrong

, p. 9425 - 9427 (2013/10/01)

Bisphosphine oxides formed highly active asymmetric Heck catalysts, which were applied in asymmetric synthesis of pharmacologically active azacycles. Olefin insertion proceeded via cis pathways, different from P,N-ligands.

Chiral silver phosphate-catalyzed cycloisomeric kinetic resolution of α-allenic alcohols

Wang, Yan,Zheng, Kuan,Hong, Ran

, p. 4096 - 4099 (2012/04/10)

A kinetic resolution of α-allenic alcohols is realized through chiral silver phosphate-catalyzed cycloisomerization with high stereoselectivity (selectivity factor up to 189) and tolerance of a variety of functional groups. A mechanistic model is proposed to interpret the origin of the high stereoselectivity and broad substrate scope.

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