136262-56-1

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 136292-93-8 Methanesulfonic acid (R)-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-propyl ester 
• 136262-54-9 (E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-5-methyl-hex-2-enoic acid ethyl ester 
• 95514-03-7 (R)-methyl 3-(tert-butyl(diphenyl)silyloxy)-2-methylpropanoate 
• 136262-53-8 (3S)-4-[(tert-butyldiphenylsilyl)oxy]-3-methylbutanenitrile 
• 123444-68-8 (S)-4-(tert-butyldiphenylsilyloxy)-3-methylbutanal 
• 95514-04-8 (S)-3-(tert-butyldiphenylsilyloxy)-2-methylpropan-1-ol 
• 136262-55-0 (E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-5-methyl-hex-2-en-1-ol 
• 136262-55-0 (2E,5S)-6-(tert-butyldiphenylsilyloxy)-5-methylhex-2-en-1-ol 
• 136786-35-1 (2R)-3-(tert-butyldiphenylsilyloxy)-2-methylpropyl p-toluenesulfonate 
• 136262-54-9 (E)-(S)-6-(tert-Butyl-diphenyl-silanyloxy)-5-methyl-hex-2-enoic acid ethyl ester 
• 1000596-44-0 4-(tert-butyldiphenylsilyloxy)-3S-methylbutanoic acid 

Downstream Products

• 136262-58-3 (3S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-5-methyl-hex-1-en-3-ol 
• 136262-59-4 tert-Butyl-((2S,4S)-4-methoxy-2-methyl-hex-5-enyloxy)-diphenyl-silane 
• 136262-72-1 (2S,3R,4S,6S)-7-(tert-Butyl-diphenyl-silanyloxy)-4-methoxy-2,6-dimethyl-heptane-1,3-diol 
• 136262-61-8 (2S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-4-methyl-pentanoic acid methyl ester 
• 136262-74-3 tert-Butyl-[(2S,4S)-4-methoxy-2-methyl-4-((4R,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-butoxy]-diphenyl-silane 
• 136262-67-4 (E)-(2S,3R,6S,7R,8S,10S)-11-(tert-Butyl-diphenyl-silanyloxy)-8-methoxy-2,4,6,10-tetramethyl-undec-4-ene-1,3,7-triol 
• 136262-62-9 [(3S,5S)-6-(tert-Butyl-diphenyl-silanyloxy)-3-methoxy-5-methyl-2-oxo-hexyl]-phosphonic acid dimethyl ester 
• 136262-71-0 (E)-(2S,3R,6R,7R,8S,10S)-11-(tert-Butyl-diphenyl-silanyloxy)-7,8-dimethoxy-2,4,6,10-tetramethyl-undec-4-ene-1,3-diol 
• 136262-68-5 (E)-(4S,5R,6S,8S)-9-(tert-Butyl-diphenyl-silanyloxy)-6-methoxy-4,8-dimethyl-2-((4R,5S)-2,2,5-trimethyl-[1,3]dioxan-4-yl)-non-2-en-5-ol 
• 136262-64-1 (E)-(3R,4S,6S)-1-{(2S,3R)-3-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-2-methyl-oxiranyl}-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxy-6-methyl-hept-1-en-3-ol 
• 136262-66-3 (E)-(2S,3R,6S,7R,8S,10S)-1-(tert-Butyl-dimethyl-silanyloxy)-11-(tert-butyl-diphenyl-silanyloxy)-8-methoxy-2,4,6,10-tetramethyl-undec-4-ene-3,7-diol 
• 136262-70-9 (E)-(2S,3R,6R,7R,8S,10S)-1-(tert-Butyl-dimethyl-silanyloxy)-11-(tert-butyl-diphenyl-silanyloxy)-7,8-dimethoxy-2,4,6,10-tetramethyl-undec-4-en-3-ol 
• 136262-63-0 (E)-(4S,6S)-1-{(2S,3R)-3-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-2-methyl-oxiranyl}-7-(tert-butyl-diphenyl-silanyloxy)-4-methoxy-6-methyl-hept-1-en-3-one 
• 136262-65-2 (2S,3R)-3-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-2-[(E)-(3R,4S,6S)-7-(tert-butyl-diphenyl-silanyloxy)-3,4-dimethoxy-6-methyl-hept-1-enyl]-2-methyl-oxirane 

Relevant academic research and scientific papers

Studies directed toward the total synthesis of tetronolide 1. An enantioselective synthesis of the octahydronaphthalene unit

An efficient enantioselective route to the octahydronaphthalene unit present in tetronolide (1), the stereochemically complex aglycone common to the tetrocarcins, a novel group of antitumor substances, is described. The sequence employs the intramolecular