136272-09-8Relevant articles and documents
Studies on organolanthanide complexes XXXVII. Reaction of dicyclopentadienylyttrium chloride with acyl chlorides in tetrahydrofuran. Acylative cleavage of the Cp-Y ?-bond and tetrahydrofuran ring
Qian, Changtao,Qiu, Aineng,Huang, Yaozeng,Chen, Wenjie
, p. 53 - 59 (2007/10/02)
Dicyclopentadienylyttrium chloride reacts with aromatic and aliphatic acid chlorides in tetrahydrofuran at room temperature, resulting in cleavage of the Cp-Y ?-bond to produce 1,5-diacylcyclopentadienes, and the acylative ring-opening of tetrahydrofuran.A possible reaction mechanism is proposed.