136295-04-0Relevant academic research and scientific papers
Cobalt Schiff Base Complex Catalyzed Dehydrogenation of Amines with t-Butyl Hydroperoxide
Maruyama, Kazushige,Kusukawa, Takahiro,Higuchi, Yoshihiko,Nishinaga, Akira
, p. 1093 - 1096 (1991)
Cobalt Schiff base complex catalyzed oxidation of secondary aromatic amines with t-butyl hydroperoxide resulted selectively in dehydrogenation to give the corresponding imines.Proposed mechanism involves electron transfer from the nitrogen atom in the substrate to t-butyloxyl or t-butylperoxyl radical produced in situ from a t-butylperoxocobalt(III) complex intermediate.
