Chemistry Letters p. 1093 - 1096 (1991)
Update date:2022-07-29
Topics:
Maruyama, Kazushige
Kusukawa, Takahiro
Higuchi, Yoshihiko
Nishinaga, Akira
Cobalt Schiff base complex catalyzed oxidation of secondary aromatic amines with t-butyl hydroperoxide resulted selectively in dehydrogenation to give the corresponding imines.Proposed mechanism involves electron transfer from the nitrogen atom in the substrate to t-butyloxyl or t-butylperoxyl radical produced in situ from a t-butylperoxocobalt(III) complex intermediate.
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