136320-64-4

Basic information

• Product Name: 1-Propanol, 3-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-
• CAS NO: 136320-64-4
• Molecular Formula: C12H18O3
• Molecular Weight: 210.273
• Mol File: 136320-64-4.mol
• Article Data: 46

Chemical Properties

• CAS DataBase Reference: 1-Propanol, 3-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanol, 3-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-(136320-64-4)
• EPA Substance Registry System: 1-Propanol, 3-[(4-methoxyphenyl)methoxy]-2-methyl-, (2R)-(136320-64-4)

Safety Data

• Hazardous Substances Data: 136320-64-4(Hazardous Substances Data)

Upstream product

• 143236-59-3 2-[(S)-3-(4-Methoxy-benzyloxy)-2-methyl-propoxy]-tetrahydro-pyran 
• 105-13-5 4-Methoxybenzyl alcohol 
• 374716-67-3 (S)-3-(4-methoxybenzyloxy)-2-methylpropyl acetate 
• 824-94-2 p-methoxybenzyl chloride 
• 123558-64-5 N-(4-methoxybenzyl)-2,2,2-trichloroacetamide 
• 2746-25-0 p-Methoxybenzyl bromide 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 882039-16-9 (1,1-dimethylethyl)(dimethyl){[(2S)-2-methyl-3-({[4-(methyloxy)phenyl]methyl}oxy)propyl]oxy}silane 
• 132969-60-9 (2S)-3-[(4-methoxybenzyl)oxy]-2-methylpropanal 
• 108-05-4 vinyl acetate 
• 374716-64-0 (+/-)-3-(4-methoxybenzyloxy)-2-methyl-1-propanol 
• 132969-71-2 methyl (2S)-[(4-methoxybenzyl)oxy]-2-methylpropanoate 

Downstream Products

• 143236-60-6 1-{[(2S)-3-bromo-2-methylpropyl]oxy}-4-methoxybenzene 
• 527743-00-6 4-methyl-benzenesulfonic acid (S)-3-(4-methoxy-benzyloxy)-2-methyl-propyl ester 
• 374716-88-8 (R)-1-benzyloxy-3-(4-methoxybenzyloxy)-2-methylpropane 
• 132969-69-8 (R)-6-(4-Methoxy-benzyloxy)-3,3,5-trimethyl-hexan-2-one 
• 136320-67-7 (2S,3R)-1-(4-Methoxy-benzyloxy)-2,4-dimethyl-pentan-3-ol 
• 136320-74-6 1-((2S,3R)-3-Benzyloxy-2,4-dimethyl-pentyloxymethyl)-4-methoxy-benzene 
• 136320-71-3 (2R,3R)-2-Isopropyl-6-[(R)-4-(4-methoxy-benzyloxy)-1,1,3-trimethyl-butyl]-3-methyl-2,3-dihydro-pyran-4-one 
• 136320-70-2 (2R,8R,9R)-9-Hydroxy-1-(4-methoxy-benzyloxy)-2,4,4,8,10-pentamethyl-undecane-5,7-dione 
• 136320-69-9 (2R,8S,9R)-9-Benzyloxy-7-hydroxy-1-(4-methoxy-benzyloxy)-2,4,4,8,10-pentamethyl-undecan-5-one 
• 914641-63-7 1-methoxy-4-([(2R)-2-methyl-3-butenyl]oxymethyl)benzene 
• 1322669-25-9 C₁₃H₂₀O₃ 
• 1322669-19-1 C₂₉H₃₈O₃Si 
• 1192344-63-0 (R)-1-((2,4-dimethylpentyloxy)methyl)-4-methoxybenzene 
• 1344072-77-0 C₂₇H₄₆O₇Si 

Relevant articles and documents

Synthetic studies toward the total synthesis of tautomycetin

The studies culminating in the synthesis of two large subunits of tautomycetin are described. The first one, fragment C1-C12 that has an anti-1,3-dimethyl system and a terminal diene unit, was accomplished in 10 linear steps in 7.4% overall yield. The second one, fragment C13-C25 which bears the sensitive anhydride framework and the majority of the stereogenic centers, was prepared in 13 linear steps (longest sequence) in 8% overall yield. Among the key transformations used, a regioselective epoxide opening, a Pd-catalyzed addition of terminal alkyne to acceptor alkyne, a Mukaiyama aldol reaction, a Yamaguchi esterification, and a homemade mild di-esterification can be cited. The chosen strategies allowed good yields, stereoselectivity, reproducibility, and scalability for several important intermediates.

Formal synthesis of tirandamycin B

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Enantioselective Hydroformylation of 1-Alkenes with Commercial Ph-BPE Ligand

A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined, and all delivered high enantioselectivity (up to 98:2 er) as well as good branch:linear ratios (up to 15:1). (Chemical Equation Presented).