136369-92-1Relevant academic research and scientific papers
Employing arynes in transition-metal-free monoarylation of aromatic tertiary amines
Bhojgude, Sachin Suresh,Kaicharla, Trinadh,Biju, Akkattu T.
, p. 5452 - 5455 (2013)
The highly monoselective N-arylation of aromatic tertiary amines using a transition-metal-free approach using arynes has been developed. The reaction afforded functionalized diaryl amines in moderate to excellent yield. High levels of functional group compatibility especially with halogen containing substrates, dyes and donor-acceptor systems, and high yields of products are the notable features of the present reaction.
TRANSITION-METAL-FREE N-ARYLATION OF TERTIARY AMINES USING ARYNES
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Paragraph 0029; 0047, (2015/01/16)
The present invention relates to transition-metal-free process for the synthesis of tertiary arylamines comprises coupling reaction between arynes and N,N-dimethyl aniline compounds in presence of 18-crown-6, KF and THF.
