136377-87-2

Upstream product

• 136320-88-2 Benzoic acid (2S,3aR,5aS,9S,9aR,9bR)-2-methoxy-9-(4-methoxy-benzyloxy)-3a,6,6,9a-tetramethyl-octahydro-naphtho[1,2-d][1,3]dioxol-9b-ylmethyl ester 
• 149-73-5 trimethyl orthoformate 
• 98-88-4 benzoyl chloride 

Downstream Products

• 136321-06-7 [(2S,3aS,5aR,9R,9aS,9bS)-2-Methoxy-9-(4-methoxy-benzyloxy)-3a,6,6,9a-tetramethyl-octahydro-naphtho[1,2-d][1,3]dioxol-9b-yl]-methanol 
• 136320-95-1 C₂₆H₃₆O₅ 
• 136320-97-3 (2S,3aR,4R,6aS,9aS,9bR)-3a-(1-Hydroxy-but-2-ynyl)-2-(4-methoxy-phenyl)-4,7,7,9b-tetramethyl-decahydro-naphtho[1,8-de][1,3]dioxin-4-ol 
• 136321-11-4 1-[(1R,2S,4aR,8R,8aS)-1,2-Dihydroxy-8-(4-methoxy-benzyloxy)-2,5,5,8a-tetramethyl-decahydro-naphthalen-1-yl]-but-2-yn-1-one 
• 136320-94-0 (4aS,6aR,10R,10aS,10bR)-10b-Hydroxy-10-(4-methoxy-benzyloxy)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-benzo[f]chromen-1-one 
• 136320-89-3 (2S,3aS,5aR,9R,9aS,9bR)-2-Methoxy-9-(4-methoxy-benzyloxy)-3a,6,6,9a-tetramethyl-octahydro-naphtho[1,2-d][1,3]dioxole-9b-carbaldehyde 
• 136321-12-5 1-[(2S,3aS,4R,6aS,9aS,9bR)-4-Hydroxy-2-(4-methoxy-phenyl)-4,7,7,9b-tetramethyl-octahydro-naphtho[1,8-de][1,3]dioxin-3a-yl]-but-2-yn-1-one 
• 136320-98-4 C₂₆H₃₄O₅ 
• 136321-10-3 (3S,4aS,6aR,10R,10aS,10bR)-10b-Hydroxy-10-(4-methoxy-benzyloxy)-3,4a,7,7,10a-pentamethyl-3-vinyl-dodecahydro-benzo[f]chromen-1-one 
• 136320-99-5 C₂₈H₃₈O₅ 
• 136320-93-9 1-[(2S,3aS,5aR,9R,9aS,9bR)-2-Methoxy-9-(4-methoxy-benzyloxy)-3a,6,6,9a-tetramethyl-octahydro-naphtho[1,2-d][1,3]dioxol-9b-yl]-but-2-yn-1-one 
• 136321-09-0 (3R,4aS,6aR,10R,10aS,10bR)-10b-Hydroxy-3-(2-hydroxy-ethyl)-10-(4-methoxy-benzyloxy)-3,4a,7,7,10a-pentamethyl-dodecahydro-benzo[f]chromen-1-one 
• 136320-96-2 Benzoic acid 1-[(1S,2S,4aR,8R,8aS)-1,2-dihydroxy-8-(4-methoxy-benzyloxy)-2,5,5,8a-tetramethyl-decahydro-naphthalen-1-yl]-but-2-ynyl ester 
• 136320-91-7 (E)-5-(tert-Butyl-diphenyl-silanyloxy)-1-[(1R,2S,4aR,8R,8aS)-1,2-dihydroxy-8-(4-methoxy-benzyloxy)-2,5,5,8a-tetramethyl-decahydro-naphthalen-1-yl]-3-methyl-pent-2-en-1-one 

Relevant academic research and scientific papers

Stereocontrolled syntheses and biological profiles of (±)-6,7-dideoxyforskolin and its 13-epimer

A stereocontrolled synthesis of the hitherto unknown (±)-6,7-dideoxyforskolin has been accomplished, incorporating controlled C-ring annulation with simultaneous creation of the stereogenic center at C-13 via oxymercuration. An alternative attempt at C-ri