Stereocontrolled syntheses and biological profiles of (±)-6,7-dideoxyforskolin and its 13-epimer

DOI: 10.1016/0040-4039(91)80618-G

Source and publish data:

Tetrahedron Letters p. 4027 - 4030 (1991)

Update date:2022-08-04

Topics:

Authors:

Hashimoto, Shun-Ichi

Ban, Masaaki

Yanagiya, Yuki

Sakata, Shinji

Ikegami, Shiro

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Article abstract of DOI:10.1016/0040-4039(91)80618-G

A stereocontrolled synthesis of the hitherto unknown (±)-6,7-dideoxyforskolin has been accomplished, incorporating controlled C-ring annulation with simultaneous creation of the stereogenic center at C-13 via oxymercuration. An alternative attempt at C-ri

Full text of DOI:10.1016/0040-4039(91)80618-G

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Product name:Benzoic acid (2S,3aR,5aS,9S,9aR,9bR)-2-methoxy-9-(4-methoxy-benzyloxy)-3a,6,6,9a-tetramethyl-octahydro-naphtho[1,2-d][1,3]dioxol-9b-ylmethyl ester

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