1363789-11-0Relevant academic research and scientific papers
GOLD-CATALYZED C-C CROSS-COUPLING OF BORON- AND SILICON-CONTAINING ARYL COMPOUNDS AND ARYLDIAZONIUM COMPOUNDS BY VISIBLE-LIGHT
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Page/Page column 44, (2018/07/29)
The present invention relates to a method for producing (functionalized) biaryls by employing a visible-light-driven, gold-catalyzed C-C cross-coupling reaction system involving boron- and silicon-containing aryl compounds and aryldiazonium compounds. Moreover, the present invention relates to the use of such boron- and silicon-containing aryl compounds and aryldiazonium compounds, as well as related gold catalysts, in the manufacture of (functionalized) biaryls.
Aryldiazonium bis(trifluoromethyl)imides
Hirschberg,Ignat'Ev,Wenda,Frohn,Willner
experimental part, p. 183 - 186 (2012/04/10)
Aryldiazonium bis(trifluoromethyl)imides, [ArN2][N(CF 3)2], are the first examples of diazonium salts with this type of anion. Their syntheses and properties will be presented and compared to aryldiazonium bis(trifluoromethylsulfonyl)imides. [ArN2][N(CF 3)2] are less stable diazonium salts in comparison to [ArN2][N(SO2CF3)2] due to the higher nucleophilicity of the [N(CF3)2]- anion.
