13653-12-8

Basic information

• Product Name: 4,4'-methylenebis[2,6-bis(hydroxymethyl)phenol]
• Synonyms: 4,4'-methylenebis[2,6-bis(hydroxymethyl)phenol]
• CAS NO: 13653-12-8
• Molecular Weight: 320.342
• Mol File: 13653-12-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 4,4'-methylenebis[2,6-bis(hydroxymethyl)phenol](CAS DataBase Reference)
• NIST Chemistry Reference: 4,4'-methylenebis[2,6-bis(hydroxymethyl)phenol](13653-12-8)
• EPA Substance Registry System: 4,4'-methylenebis[2,6-bis(hydroxymethyl)phenol](13653-12-8)

Safety Data

• Hazardous Substances Data: 13653-12-8(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 620-92-8 bis-(4-hydroxyphenyl)methane 
• 108-95-2 phenol 
• 121-45-9 phosphorous acid trimethyl ester 

Downstream Products

• 120265-34-1 bis-[3,5-bis-(5-bromo-2-hydroxy-benzyl)-4-hydroxy-phenyl]-methane 
• 35924-12-0 bis-[4-hydroxy-3,5-bis-(2-hydroxy-3,5-dimethyl-benzyl)-phenyl]-methane 
• 147197-47-5 3,5,3',5'-tetrakis(chloromethyl)-4,4'-dihydroxydiphenylmethane 
• 128792-97-2 bis<3,5-bis(hydroxymethyl)-4-methoxyphenyl>methane 
• 50-00-0 formaldehyd 
• 7732-18-5 water 
• 147197-53-3 C₂₁H₂₄Cl₄O₂ 
• 147197-55-5 [5-(3,5-Bis-carboxymethylsulfanylmethyl-4-ethoxy-benzyl)-3-carboxymethylsulfanylmethyl-2-ethoxy-benzylsulfanyl]-acetic acid 
• 147197-54-4 [2-Ethoxy-5-(4-ethoxy-3,5-bis-ethoxycarbonylmethylsulfanylmethyl-benzyl)-3-ethoxycarbonylmethylsulfanylmethyl-benzylsulfanyl]-acetic acid ethyl ester 
• 1622135-08-3 C₂₉H₂₈O₁₀ 
• 120830-40-2 bis-(4-hydroxy-3,5-disalicyl-phenyl)-methane 
• 152492-58-5 4,4'-bis(4-bromobutoxy)-3,5,3',5'-tetrakis(ethoxycarbonylmethylthiomethyl)-4,4'-diphenylmethane 
• 152492-57-4 3,5,3',5'-tetrakis(ethoxycarbonylmethylthiomethyl)-4,4'-dihydroxydiphenylmethane 
• 147197-52-2 [2-Ethoxy-5-(4-ethoxy-3,5-bis-hydroxymethyl-benzyl)-3-hydroxymethyl-phenyl]-methanol 

Relevant articles and documents

A new prepolymer of resol phenol-formaldehyde resin

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MULTI-FUNCTIONAL ACRYLATES

Disclosed herein are derivatives of phenolic and melamine compounds, methods of making these derivatives, and methods of using them. The compounds include phenolic and melamine compounds with multi-functional acrylate groups, polyethylene glycol and amino groups. The compounds may be cured to form resins that may be used in a variety of applications, such as paints, hydrogels, polyacrylate super absorbent polymers (SAPs), adhesives, composites, sealants, fillers, fire retardants, crosslinking agents, and the like.

Spectral assignments and reference data: A 13C NMR study of the methylol derivatives of 2,4′- and 4,4′-dihydroxydiphenylmethanes found in resol phenol-formaldehyde resins

A total of 13 of the 16 possible methylol derivatives of 2,4′- and 4,4′-dihydroxydiphenylmethane have been synthesized, isolated, and identified. These compounds are found as intermediates in the cure process of resol phenol-formaldehyde (PF) resins. Analysis of the 13C NMR spectra (in acetone-d6) of these compounds provided a way to evaluate the seven methylolphenol ring types (methylol derivatives of 2-hydroxyphenyl and 4-hydroxyphenyl rings) found in typical resol PF resins using the ipso carbon region from 150 to 160 ppm. A simple diagnostic test was developed using the chemical shift values of the methylol methylene carbon atoms to identify the presence of intermediates containing either a 2-hydroxyphenyl or a 4-hydroxyphenyl ring. Using these data it is now possible to analyze the major components in extracted prepreg PF resins. Copyright