136603-89-9Relevant academic research and scientific papers
A simple, highly regioselective, one-pot stereoselective synthesis of tertiary α-hydroxyesters: a tandem oxidation/benzilic ester rearrangement
Marques, Carolina Sílva,Moura, Nuno,Burke, Anthony J.
, p. 6049 - 6052 (2007/10/03)
This letter describes a simple, highly regioselective, stereoselective one-pot tandem oxidation/benzilic ester rearrangement protocol for the conversion of α-hydroxyketones to tertiary α-hydroxyesters.
MEDIUM EFFECT ON THE DIRECTION OF THE REACTION OF 3-CHLORO-1,3-DIPHENYL-1,2-PROPANEDIONE WITH ORTHO-PHENYLENEDIAMINE
Mamedov, V. A.,Polushina, V. L.,Mertsalova, F. F.,Nuretdinov, I. A.,Plyamovatyi, A. Kh.
, p. 1472 - 1474 (2007/10/02)
The reaction of 3-chloro-1,3-diphenyl-1,2-propanedione (I) with ortho-phenylenediamine in acetic acid gave 2-phenyl-3-(α-chlorobenzyl)quinoxaline (II).This reaction in methanol with MeONa gave 2-(α-hydroxybenzylidene)-3-phenyl-1,4-dihydroquinoxaline (VI).
