1366610-45-8

Basic information

• Product Name: methyl (E)-6-(diphenylphosphinyl)-5-butylthio-5-hexenoate
• Synonyms: methyl (E)-6-(diphenylphosphinyl)-5-butylthio-5-hexenoate
• CAS NO: 1366610-45-8
• Molecular Weight: 416.521
• Mol File: 1366610-45-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (E)-6-(diphenylphosphinyl)-5-butylthio-5-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-6-(diphenylphosphinyl)-5-butylthio-5-hexenoate(1366610-45-8)
• EPA Substance Registry System: methyl (E)-6-(diphenylphosphinyl)-5-butylthio-5-hexenoate(1366610-45-8)

Safety Data

• Hazardous Substances Data: 1366610-45-8(Hazardous Substances Data)

Upstream product

• 77758-51-1 methyl hex-5-ynoate 
• 52372-89-1 Diphenylthiophosphinsaeure-S-n-butylester 

Relevant articles and documents

Palladium-catalyzed phosphinylthiolation of terminal alkynes

Phosphinylthiolation of terminal alkynes with Ph2P(O)SBu or a related compound proceeds in the presence of a palladium-PEt3 catalyst system. Activity and stereoselectivity are highly dependent on the nature of solvent, ethylbenzene, and n-hexanol (or t-amyl alcohol) being E- and Z-selective, respectively.