13674-19-6

Basic information

• Product Name: Cyclohexanemethanol, 4-(1-methylethyl)-, trans-
• Synonyms: Cyclohexanemethanol, 4-(1-methylethyl)-, trans-;trans-p-Menthan-7-ol
• CAS NO: 13674-19-6
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.27
• Mol File: 13674-19-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 124 °C(Press: 22 Torr)
• Appearance: /
• Density: 0.882±0.06 g/cm3(Predicted)
• PKA: 15.05±0.10(Predicted)
• CAS DataBase Reference: Cyclohexanemethanol, 4-(1-methylethyl)-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanemethanol, 4-(1-methylethyl)-, trans-(13674-19-6)
• EPA Substance Registry System: Cyclohexanemethanol, 4-(1-methylethyl)-, trans-(13674-19-6)

Safety Data

• Hazardous Substances Data: 13674-19-6(Hazardous Substances Data)

Usage

InChI:InChI=1S/C10H20O/c1-8(2)10-5-3-9(7-11)4-6-10/h8-11H,3-7H2,1-2H3

Upstream product

• 99-87-6 4-methylisopropylbenzene 
• 116473-59-7 4-(1-methoxy-1-methylethyl)-benzaldehyde dimethyl acetal 
• 536-59-4 perillol 
• 6931-54-0 β-pinene oxide 
• 122-03-2 (4-isopropylbenzaldehyde) 
• 23963-70-4 (S)-4-Isopropyl-cyclohex-1-enecarbaldehyde 
• 153308-19-1 trans-7-methoxymethyl-2-menthane 
• 35836-73-8 (1R)-(-)-nopol 
• 64-17-5 ethanol 
• 88166-24-9 4-isopropylcyclohexane-1-carbaldehyde 
• 555-31-7 aluminum isopropoxide 
• 67-63-0 isopropyl alcohol 

Downstream Products

• 31509-46-3 trans-1-Toluolsulfonyloxymethyl-4-isopropyl-cyclohexan 
• 1678-82-6 trans-1,4-menthane 
• 32533-97-4 4-Isopropyl-cyclohexanecarbaldehyde 
• 31509-43-0 7-(3.5-dinitro-benzoyloxy)-trans-p-methane 

Relevant articles and documents

Preparation and utilization of perillyl acetate

Perillyl acetate is a fragrance compound that was prepared by the reaction of β-pinenoxide with acetic anhydride and using acetic acid as an acid catalyst. Several selected catalysts were tested (homogenous: phosphoric acid, boric acid, acetic acid, and citric acid; heterogeneous: zeolite USY, SSA, and montmorillonite K-10) and the reaction conditions optimized for this reaction. The yield 78.7 % of perillyl acetate was obtained. Mayol (4- isopropylcyclohexylmethanol), a valuable fragrance compound, was further obtained by a two-step synthesis from perillyl acetate. Firstly, perillyl acetate was saponified to perillyl alcohol. The yield of alcohol was 94.4 %. The last step of the entire preparation was the hydrogenation of perillyl alcohol to Mayol. The yield of the desired product of this reaction was 94.6 %. Springer Science+Business Media B.V. 2012.

CONTINUOUS METHOD FOR PRODUCING SUBSTITUTED CYCLOHEXYLMETHANOLS

The present invention relates to a continuous process for preparing para-alkyl-substituted cyclohexylmethanols, especially 4-isopropylcyclohexylmethanol, by catalytically hydrogenating the corresponding aldehydes or ketones in the presence of hydrogen and in the presence of a catalyst which comprises, as an active metal, ruthenium applied to a support, the support comprising Al2O3 and/or SiO2, and the catalyst being used in the form of a fixed bed catalyst in a hydrogenation reactor or in a plurality of hydrogenation reactors connected in series.