13684-98-5

Basic information

• Product Name: Benzene, (2-iodo-1-methoxyethyl)-
• CAS NO: 13684-98-5
• Molecular Formula: C9H11IO
• Molecular Weight: 262.09
• Mol File: 13684-98-5.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Benzene, (2-iodo-1-methoxyethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-iodo-1-methoxyethyl)-(13684-98-5)
• EPA Substance Registry System: Benzene, (2-iodo-1-methoxyethyl)-(13684-98-5)

Safety Data

• Hazardous Substances Data: 13684-98-5(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 67-56-1 methanol 
• 37011-27-1 C₁₃H₁₇O₅Tl 
• 37898-11-6 C₆H₅CH(OCH₃)CH₂(HgCH₃CO₂) 
• 26466-04-6 methyl hypoiodite 

Downstream Products

• 6721-66-0 (β-methoxy-phenethyl)-dimethyl-amine 
• 28437-97-0 2-methyl-4-phenyl-4,5-dihydrooxazole 
• 122-78-1 phenylacetaldehyde 
• 101-48-4 phenylacetaldehyde dimethyl acetal 
• 88147-91-5 (β-methoxy-phenethyl)-trimethyl-ammonium; iodide 
• 66702-75-8 2-nitrato-1-phenylethanone 
• 62054-83-5 (2-Iodo-1,1-dimethoxy-ethyl)-benzene 
• 4636-16-2 iodoacetophenone 
• 4747-13-1 α-methoxystyrene 

Relevant articles and documents

4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid: New recyclable hypervalent iodine reagents for vicinal halomethoxylation of unsaturated compounds

4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid are convenient recyclable hypervalent iodine reagents for vicinal chloromethoxylation or iodomethoxylation of unsaturated compounds. The reactivity of these reagents in the reaction of vicinal halomethoxylation is generally similar to dichloroiodobenzene and the advantage of their use is that the reduced forms of these reagents can be easily separated from the reaction mixture and reused for the regeneration of the reagents.

Regioselective vicinal functionalization of unactivated alkenes with sulfonium iodate(i) reagents under metal-free conditions

Metal-free, molecular iodine-free direct 1,2-difunctionalization of unactivated alkenes has been reported. The sulfonium iodate(i) reagent efficiently promoted the intermolecular vicinal iodo-functionalization of a diverse range of olefins in a stereo and regioselective manner. This method enables the divergent and straightforward preparation of synthetically useful functionalities; β-iodocarboxylates, β-iodohydrins, and β-iodoethers in a one-step process. Further interconversion of iodo-functionalized derivatives allows easy access to valuable synthetic intermediates en route to biologically active molecules.

PROCESS FOR THE PREPARATION OF N-IODOAMIDES

The present invention provides new stable crystalline N-iodoamides - 1-iodo- 3,5,5-trimethylhydantoin (1-ITMH) and 3-iodo-4,4-dimethyl-2-oxazolidinone (IDMO). The present invention further provides a process for the preparation of organic iodides using N-iodoamides of this invention and recovery of the amide co-products from waste water.