13684-99-6Relevant academic research and scientific papers
Envirocat (K10-MX)-catalyzed regioselective transformation of alkenes into iodohydrins and β-iodo ethers and further conversion of iodohydrins to epoxides using Al2O3-Na2Co3 under MWI
Shallu,Sharma,Singh, Jasvinder
experimental part, p. 1306 - 1324 (2012/04/04)
Commercial K10 clay was converted to extremely efficient and environmentally friendly catalyst K10-MX for the preparation of iodohydrins and β-iodo ethers from alkenes (terminal as well as internal) using microwave irradiation. This method was further extended for the conversion of alkenes to epoxides via iodohydrin intermediate in a one-pot reaction system. Copyright Taylor & Francis Group, LLC.
An improved synthesis of β-iodo ethers and iodohydrins from alkenes
Sanseverino, Antonio M.,De Mattos, Marcio C. S.
, p. 1584 - 1586 (2007/10/03)
The preparation of diverse β-iodo ethers and iodohydrins is efficiently achieved in mild conditions by reaction of alkenes with two equivalents of I2 and alcohols (EtOH, i-PrOH, t-BuOH) or water, respectively.
SYNTHESIS OF β-IODO-t-BUTYL AND METHYL ETHERS FROM THE REACTION OF ALKENES WITH t-BUTYL AND METHYL HYPOIODITES
Glover, Stephen A.,Goosen, Andre
, p. 2005 - 2008 (2007/10/02)
t-Butyl or methyl hypoiodite, generated from potassium t-butoxide or sodium methoxide and iodine monochloride, react with olefins via a bridged iodonium ion intermediate giving the trans-vicinal iodo-t-butyl or -methyl ethers.
