13697-98-8Relevant academic research and scientific papers
Synthesis of trivalent phosphorus derivatives by light-induced dibromophosphination of akenes
Krivchun,Khramchikhin
, p. 1527 - 1530 (2017/09/01)
Light-induced dibromophosphination of alkenes was studied. Dehydrobromination of the synthesized bromoalkylphosphonous dibromides gave the corresponding dibromophosphinoalkenes which were converted into alkenylphosphonous acids and their cyclic esters, benzo[1,3,2]dioxaphospholes.
Complexes of transition metals with α,β-unsaturated phosphines
Reznikov,Krivchun,Bel'skii,Skvortsov
, p. 1032 - 1036 (2007/10/03)
Pd(II), Pt(II), Ni(II) complexes with (cyclohexenyl)diphenylphosphine and diphenyl(l-phenylvinyl)phosphine are synthesized. The 1H and 31P NMR and IR spectra of the products, as well as their X-ray structural analyses are reported.
STEREOCHEMICAL STUDIES-XXIX STEREOCHEMISTRY OF THE ADDITION OF PHOSPHOROUS TRIBROMIDE TO OLEFINS
Zefirov, Nikolai S.,Zyk, Nikolai V.,Borisenko, Analtolii A.,Krysin, Mikhail Yu.,Schestakova, Tamara G.
, p. 3145 - 3149 (2007/10/02)
The stereochemical course of PBr3 addition to a series of cycloolefins has been found to depend crucially on the olefinic structure and the reaction proceeds in highly stereoselective fashion either as trans-(cyclohexene) or as cis-(norbornene and related
