332402-27-4

Upstream product

• 110-83-8 cyclohexene 
• 13697-98-8 2-bromo-1-(dibromophosphino)cyclohexane 

Downstream Products

• 38868-16-5 cyclohex-1-en-1-yl(diphenyl)phosphine oxide 
• 82201-23-8 (1-cyclohexenyl)diphenylphosphine 
• 67990-88-9 2-Cyclohex-1-enyl-benzo[1,3,2]dioxaphosphole 2-oxide 

Relevant academic research and scientific papers

Synthesis of trivalent phosphorus derivatives by light-induced dibromophosphination of akenes

Light-induced dibromophosphination of alkenes was studied. Dehydrobromination of the synthesized bromoalkylphosphonous dibromides gave the corresponding dibromophosphinoalkenes which were converted into alkenylphosphonous acids and their cyclic esters, benzo[1,3,2]dioxaphospholes.

Complexes of transition metals with α,β-unsaturated phosphines

Pd(II), Pt(II), Ni(II) complexes with (cyclohexenyl)diphenylphosphine and diphenyl(l-phenylvinyl)phosphine are synthesized. The 1H and 31P NMR and IR spectra of the products, as well as their X-ray structural analyses are reported.