137022-49-2

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 91266-03-4 tert-butyl-pent-4-ynyloxy-diphenyl-silane 
• 5390-04-5 pent-1-yn-5-ol 
• 86990-96-7 {3-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-oxiranyl}-methanol 
• 118419-29-7 6-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)hex-2-yn-1-ol 
• 118419-30-0 (Z)-6-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)hex-2-en-1-ol 

Downstream Products

• 137022-43-6 (E)-3-{3-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-oxiranyl}-acrylic acid methyl ester 
• 137120-25-3 (2R,3S)-2-(3-Hydroxypropyl)tetrahydropyran-3-ol 

Relevant academic research and scientific papers

Enantioselective synthesis of the AB ring fragment of gambiertoxin 4B. Implication for the absolute configuration of gambiertoxin 4B and ciguatoxin

The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5R configuration.