86990-96-7Relevant articles and documents
Enantioselective synthesis of the AB ring fragment of gambiertoxin 4B. Implication for the absolute configuration of gambiertoxin 4B and ciguatoxin
Suzuki, Toshio,Sato, Ohki,Hirama, Masahiro,Yamamoto, Yoshinori,Murata, Michio,Yasumoto, Takeshi,Harada, Nobuyuki
, p. 4505 - 4508 (1991)
The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5R configuration.
Rhodium-catalyzed endo -selective epoxide-opening cascades: formal synthesis of (-)-brevisin
Armbrust, Kurt W.,Beaver, Matthew G.,Jamison, Timothy F.
, p. 6941 - 6946 (2015/06/16)
[Rh(CO)2Cl]2 is as an effective catalyst for endo-selective cyclizations and cascades of epoxy-(E)-enoate alcohols, thus enabling the synthesis of oxepanes and oxepane-containing polyethers from di- and trisubstituted epoxides. Synth