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(Z)-6-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)hex-2-en-1-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

118419-30-0

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118419-30-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 118419-30-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,8,4,1 and 9 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 118419-30:
(8*1)+(7*1)+(6*8)+(5*4)+(4*1)+(3*9)+(2*3)+(1*0)=120
120 % 10 = 0
So 118419-30-0 is a valid CAS Registry Number.

118419-30-0Relevant articles and documents

Allylation of nitrosobenzene with pinacol allylboronates. A regioselective complement to peroxide oxidation

Kyne, Robert E.,Ryan, Michael C.,Kliman, Laura T.,Morken, James P.

supporting information; experimental part, p. 3796 - 3799 (2010/10/21)

Addition of nitrosobenzene to pinacol allylboronates leads to oxidation of the organoboron with concomitant rearrangement of the substrate alkene. This reaction appears to proceed by allylboration of the nitroso group in analogy to carbonyl and imine allylation reactions. Remarkably, the N-O bond is cleaved during the reaction such that simple alcohols are the final reaction product.

Attempt to rationalize the diastereoselectivity in the addition of ester enolate to optically active α,β-epoxyaldehydes

Nacro,Baltas,Gorrichon

, p. 14013 - 14030 (2007/10/03)

Aldol condensations on α,β-epoxyaldehyde having a remote alkoxy group have been realized. A rationalization of the outcome of this condensation is discussed, relying on the dominant conformers revealed by molecular modeling of anti and syn γ,δ-epoxy β-hyd

Intramolecular termination of radical-polar crossover reactions

Murphy, John A.,Rasheed, Faiza,Roome, Stephen J.,Scott, Karen A.,Lewis, Norman

, p. 2331 - 2339 (2007/10/03)

Cyclic ethers result from intramolecular trapping of cations formed through the radical-polar crossover process.

Enantioselective synthesis of the AB ring fragment of gambiertoxin 4B. Implication for the absolute configuration of gambiertoxin 4B and ciguatoxin

Suzuki, Toshio,Sato, Ohki,Hirama, Masahiro,Yamamoto, Yoshinori,Murata, Michio,Yasumoto, Takeshi,Harada, Nobuyuki

, p. 4505 - 4508 (2007/10/02)

The AB ring framework of gambiertoxin 4B which has a butadienyl substituent on the tetrahydrooxepin ring A has been synthesized stereoselectively and its CD spectrum suggests that gambiertoxin 4B and ciguatoxin have 5R configuration.

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