1370713-50-0

Basic information

• Product Name: 1-[4-(1-ethoxy-2,2,2-trifluoro-1-trimethylsiloxyethyl)-3-methylphenyl]-2-methylpropan-1-one
• Synonyms: 1-[4-(1-ethoxy-2,2,2-trifluoro-1-trimethylsiloxyethyl)-3-methylphenyl]-2-methylpropan-1-one
• CAS NO: 1370713-50-0
• Molecular Weight: 376.491
• Mol File: 1370713-50-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[4-(1-ethoxy-2,2,2-trifluoro-1-trimethylsiloxyethyl)-3-methylphenyl]-2-methylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[4-(1-ethoxy-2,2,2-trifluoro-1-trimethylsiloxyethyl)-3-methylphenyl]-2-methylpropan-1-one(1370713-50-0)
• EPA Substance Registry System: 1-[4-(1-ethoxy-2,2,2-trifluoro-1-trimethylsiloxyethyl)-3-methylphenyl]-2-methylpropan-1-one(1370713-50-0)

Safety Data

• Hazardous Substances Data: 1370713-50-0(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 383-63-1 ethyl trifluoroacetate, 
• 57494-03-8 2-methyl-1-(3-methylphenyl)propan-1-one 

Downstream Products

• 1370713-56-6 2-methyl-1-(3-methyl-4-trifluoroacetylphenyl)propan-1-one 

Relevant articles and documents

Abnormal and direct para-trifluoroacetylation of branched alkyl phenyl ketones by magnesium-promoted reductive aromatic substitution

Magnesium-promoted reduction of branched alkyl phenyl ketones in the presence of ethyl trifluoroacetate and chlorotri-methylsilane in N,N-dimethylformamide (DMF), followed by air oxidation, and the subsequent treatment of tetrabutylammonium fluoride brought about selective and efficient formation of the corresponding aromatic para-substituted diketones possessing a tri-fluoroacetyl group in good yields through abnormal addition toward the para positions of the aromatic ketones in good yields. Georg Thieme Verlag Stuttgart · New York.